Thermal conductivity, diffusivity and specific heat capacity of as-grown, degenerate single-crystalline ZnGa2O4

This work provides the first experimental determination of the low-temperature thermal properties for novel highly pure single-crystalline ZnGa2O4. The temperature dependence of the thermal conductivity, diffusivity and specific heat capacity of as-grown, degenerated ZnGa2O4 single crystals is measured using the 2ω-method between T = 27 K and room temperature. At room temperature the thermal diffusivity is D ≈ 6.9 · 10−6 m2s, the thermal conductivity is λ ≈ 22.9 W mK−1 and the specific heat capacity is CV ≈ 537 J kgK−1. The thermal conductivity increases with decreasing temperatures due to reduced phonon-phonon Umklapp scattering down to T = 50 K. For lower temperatures the thermal conductivity is limited by boundary scattering.Deutsche Forschungsgemeinschafthttps://doi.org/10.13039/501100001659Peer Reviewe