Add to ORKGReactions of active methylene compounds HA (malononitrile, \u3b2-diketones, cyclopentadiene) with the dioxygen adduct [Rh(dppe)O2]BF4 give new hydroperoxorhodium(III) complexes of the type [Rh(dppe)(A)OOH]BF4. The complexes readily convert PPh3 into OPPh3, but do not oxidise ketones or olefins, which instead undergo extensive isomerization
A series of mononuclear hydroperoxo and tert-butylperoxo complexes L2M(Rx)(OOR) (L = 1/2, diphosphin...
Two oxorhenium(V) complexes with bidentate phosphine ligands were synthesized and isolated as [ReOCl...
The synthesis and characterization of a class of complexes of the type P2Pt(Rx)(COOH) (P2 = (PPh3)2,...
The rhodium(I) complexes [Rh(LL)(NBD)]BF4 and [Rh(LL)]BF4 (LL=diphosphines, bidentate phosphorus and...
An examination of the reactions of ReH7(PPh3) 2 with Hhq (2-hydroxyquinoline) and Hmq (2-mercaptoqui...
A series of mononuclear hydroperoxo and tert-butylperoxo complexes L2M(Rx)(OOR) (L = ½ diphosphine o...
The feasibility of oxidative addition of the P-H bond of PHPh2 to a series of rhodium complexes to g...
Rhodium complexes containing phosphorous based ligands have been extensively studied for their abili...
The feasibility of oxidative addition of the P−H bond of PHPh2 to a series of rhodium complexes to g...
A challenging goal of inorganic chemistry involves understanding the role transition metals play in ...
Hydroamination of alkenes is an important process for the production of alkylated amines, which are ...
Complexes with terminal phosphanido (M—PR2) functionalities are believed to be crucial intermediates...
Reactions of the aryl complexes Rh(aryl){κ3-P,O,P-[xant(PiPr2)2]} (1; aryl = 3,5-Me2C6H3 (a), C6H5 (...
Rhodium complex, [Rh2(PPh3)4(mu-OH) 2] containing bridging hydroxo ligands, smoothly reacts with [HM...
The ligand Ph2PC6H4(CH2N(Me)CO(Et)) reacts with (bis(diphenylphosphino)butane) (2,5-norbornadiene)rh...
A series of mononuclear hydroperoxo and tert-butylperoxo complexes L2M(Rx)(OOR) (L = 1/2, diphosphin...
Two oxorhenium(V) complexes with bidentate phosphine ligands were synthesized and isolated as [ReOCl...
The synthesis and characterization of a class of complexes of the type P2Pt(Rx)(COOH) (P2 = (PPh3)2,...
The rhodium(I) complexes [Rh(LL)(NBD)]BF4 and [Rh(LL)]BF4 (LL=diphosphines, bidentate phosphorus and...
An examination of the reactions of ReH7(PPh3) 2 with Hhq (2-hydroxyquinoline) and Hmq (2-mercaptoqui...
A series of mononuclear hydroperoxo and tert-butylperoxo complexes L2M(Rx)(OOR) (L = ½ diphosphine o...
The feasibility of oxidative addition of the P-H bond of PHPh2 to a series of rhodium complexes to g...
Rhodium complexes containing phosphorous based ligands have been extensively studied for their abili...
The feasibility of oxidative addition of the P−H bond of PHPh2 to a series of rhodium complexes to g...
A challenging goal of inorganic chemistry involves understanding the role transition metals play in ...
Hydroamination of alkenes is an important process for the production of alkylated amines, which are ...
Complexes with terminal phosphanido (M—PR2) functionalities are believed to be crucial intermediates...
Reactions of the aryl complexes Rh(aryl){κ3-P,O,P-[xant(PiPr2)2]} (1; aryl = 3,5-Me2C6H3 (a), C6H5 (...
Rhodium complex, [Rh2(PPh3)4(mu-OH) 2] containing bridging hydroxo ligands, smoothly reacts with [HM...
The ligand Ph2PC6H4(CH2N(Me)CO(Et)) reacts with (bis(diphenylphosphino)butane) (2,5-norbornadiene)rh...
A series of mononuclear hydroperoxo and tert-butylperoxo complexes L2M(Rx)(OOR) (L = 1/2, diphosphin...
Two oxorhenium(V) complexes with bidentate phosphine ligands were synthesized and isolated as [ReOCl...
The synthesis and characterization of a class of complexes of the type P2Pt(Rx)(COOH) (P2 = (PPh3)2,...