Cationic cobalt(I) carbonyl complexes containing secondary or tertiary phosphines. A direct synthesis from cobalt(II) salts.

RIGO P.
BRESSAN M.
MORVILLO, ANTONINO

Publication date

January 1976

Publisher

Elsevier BV:PO Box 211, 1000 AE Amsterdam Netherlands:011 31 20 4853757, 011 31 20 4853642, 011 31 20 4853641, EMAIL: nlinfo-f@elsevier.nl, INTERNET: http://www.elsevier.nl, Fax: 011 31 20 4853598

Abstract

Cobalt(I) carbonyl complexes of formula [Co(CO)n(P)5−n]ClO4 (n = 1, 2, 3; P = secondary or tertiary phosphine) have been prepared by reaction of CO under ambient conditions with Co(ClO4)2 · 6H2O and phosphine in isopropyl alcohol. The chemical and spectroscopic properties of these complexes are described and the stoichiometry and mechanism of the carbonylation reaction discussed

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Cationic cobalt(I) carbonyl complexes containing secondary or tertiary phosphines. A direct synthesis from cobalt(II) salts.

Abstract

Extracted data

Cationic cobalt(I) carbonyl complexes containing secondary or tertiary phosphines. A direct synthesis from cobalt(II) salts.

Abstract

Extracted data

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