This Thesis focuses on vapor bubbles and evaporating sessile drops, and on the effect of an external electric field on such processes. These apparently simple systems encompass a huge number of physical phenomena at different scales, which make them still not completely understood nowadays. A bubble and a drop have much in common, and in particular the presence of a liquid-vapor interface and of a triple region. Despite that, the processes in which are involved - boiling and evaporation respectively - are distinct. The use of an external electric field by means of an electrode has potential beneficial effects from the heat transfer point of view for both boiling as well as evaporation. In reduced gravity environments, it is especially accen...