Spin Photochemistry: Electron Spin Multiplicity as a Tool for Reactivity and Selectivity Control

  • Griesbeck, Axel
  • Bozkus, Seyma
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Publication date
October 2021
Publisher
Swiss Chemical Society
Language
English

Abstract

Spin chemistry involving small organic molecules without heavy atoms is highly sensitive to spin-orbit-coupling (SOC) modulating biradical conformation as well as hyperfine coupling (HFC) modulating magnetic isotope interactions. Several easily available reaction properties such as chemo-, regio-, and diastereoselectivity as well as quantum yields serve as analytical tools to follow intersystem crossing dynamics and allows titrating spin selectivities

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