An investigation of nanostructured thin film alpha-MoO3 based supercapacitor electrodes in an aqueous electrolyte

International audienceThe potential for MoO use as a supercapacitor electrode in aqueous electrolytes was investigated. α-MoO nanobelts were synthesized using a hydrothermal method and then thin-film electrodes were manufactured by spray deposition. Electrochemical testing in several aqueous electrolytes showed significant charge storage in 1 M HSO with a complex electrochemical activity that was further investigated by X-ray photoelectron spectroscopy and various electrochemical characterization methods. In a 0-1 V (vs Ag/AgCl) electrochemical window, MoO was reduced to a mixture of lower valence oxides with concentrations varying as Mo (5+) > Mo (4+) > Mo (6+), with MoO as the main component at potentials below 0.185 V (vs Ag/AgCl). The degree of redox reversibility was evaluated in order to optimize the electrochemical window for enhanced cyclability. A moderate capacitance of 8.8 F g (64 μF cm) was fully retained for 720 cycles in an optimized electrochemical window of 0.26-0.43 V (vs Ag/AgCl)