Add to ORKG5f covalency in [U(C7H7)2]- was probed with carbon K-edge X-ray absorption spectroscopy (XAS) and electronic structure theory. The results revealed U 5f orbital participation in δ-bonding in both the ground- and core-excited states; additional 5f ϕ-mixing is observed in the core-excited states. Comparisons with U(C8H8)2 show greater δ-covalency for [U(C7H7)2]-
The electronic structure and mechanical properties Of UC2 and U2C3 have been systematically investig...
A systematic X-ray absorption study at the U 3d, 4d, and 4f edges of UO2 was performed, and the data...
The electronic structures of a series of uranium hexahalide and uranyl tetrahalide complexes were si...
5f covalency in [U(C7H7)2]- was probed with carbon K-edge X-ray absorption spectroscopy (XAS) and el...
Evidence for metal-carbon orbital mixing in thorocene and uranocene was determined from DFT calculat...
Correction for 'Enhanced 5f-δ bonding in [U(C7H7)2]-: C K-edge XAS, magnetism, and ab initio calcula...
Abstract The electronic structure of UC $$_x$$ x (x = 0.9, 1.0, 1.1, 2.0) was studied by means of x-...
Evaluating the nature of chemical bonding for actinide elements represents one of the most important...
Relativistic multireference ab initio wave function calculations within the restricted active space ...
Evaluating the nature of chemical bonding for actinide elements represents one of the most important...
International audienceOne of the long standing debates in actinide chemistry is the level of localiz...
ABSTRACT: The electronic structure of the arene-bridged complex (μ-toluene)U2(N[ tBu]Ar)4 (1a2-μ-tol...
Herein, computational calculation has been used to study the electronic structure and bonding of ura...
The synthesis, structure, and reactivity of a uranium metallacyclopropene were comprehensively studi...
International audienceThe multifaceted character of 5f electrons in actinide materials, from localiz...
The electronic structure and mechanical properties Of UC2 and U2C3 have been systematically investig...
A systematic X-ray absorption study at the U 3d, 4d, and 4f edges of UO2 was performed, and the data...
The electronic structures of a series of uranium hexahalide and uranyl tetrahalide complexes were si...
5f covalency in [U(C7H7)2]- was probed with carbon K-edge X-ray absorption spectroscopy (XAS) and el...
Evidence for metal-carbon orbital mixing in thorocene and uranocene was determined from DFT calculat...
Correction for 'Enhanced 5f-δ bonding in [U(C7H7)2]-: C K-edge XAS, magnetism, and ab initio calcula...
Abstract The electronic structure of UC $$_x$$ x (x = 0.9, 1.0, 1.1, 2.0) was studied by means of x-...
Evaluating the nature of chemical bonding for actinide elements represents one of the most important...
Relativistic multireference ab initio wave function calculations within the restricted active space ...
Evaluating the nature of chemical bonding for actinide elements represents one of the most important...
International audienceOne of the long standing debates in actinide chemistry is the level of localiz...
ABSTRACT: The electronic structure of the arene-bridged complex (μ-toluene)U2(N[ tBu]Ar)4 (1a2-μ-tol...
Herein, computational calculation has been used to study the electronic structure and bonding of ura...
The synthesis, structure, and reactivity of a uranium metallacyclopropene were comprehensively studi...
International audienceThe multifaceted character of 5f electrons in actinide materials, from localiz...
The electronic structure and mechanical properties Of UC2 and U2C3 have been systematically investig...
A systematic X-ray absorption study at the U 3d, 4d, and 4f edges of UO2 was performed, and the data...
The electronic structures of a series of uranium hexahalide and uranyl tetrahalide complexes were si...