We study the relativistic, inviscid, advective accretion flow around the black holes and investigate a key feature of the accretion flow, namely the shock waves. We observe that the shock-induced accretion solutions are prevalent and such solutions are commonly obtained for a wide range of the flow parameters, such as energy (${\cal E}$) and angular momentum ($\lambda$), around the black holes of spin value $0\le a_{\rm k} < 1$. When the shock is dissipative in nature, a part of the accretion energy is released through the upper and lower surfaces of the disc at the location of the shock transition. We find that the maximum accretion energies that can be extracted at the dissipative shock ($\Delta{\cal E}^{\rm max}$) are $\sim 1\%$ and $\si...