Chemielectron and chemiion spectra resulting from the reactions of effusive beams of Ca, and Sr and Ba (in their ground 1S states) with ground state molecular oxygen O2(X 3Σ- g) have been recorded using electron spectroscopy and mass spectrometry. The chemielectron spectra are similar for all three reactions exhibiting a strong near-zero energy band and another band at higher electron energies. The chemiion spectra show O+ 2, M+ and M2O+ 2 as the major ions. The total ion current as well as the individual ion intensities, have been recorded as a function of the extraction potential on the reaction cell. The results obtained indicate that the metal oxide dimer ion is the primary chemiion, formed via an associative ionization reaction of a me...
peer reviewedDissociative ionization in O2 has been examined by means of a retarding potential lens ...
Equilibrium thermochemical analyses are employed to describe the vaporization processes of metals an...
1.Introduction. Electrons and metal ions in fluids play important roles in many aspects of chemlca...
The U+O chemi-ionization reaction has been investigated by quantum chemical methods. Potential-energ...
The Sm+O chemiionization reaction has been investigated theoretically using a method that allows for...
Most of this thesis is concerned with recording electron spectra arising either from photoionisation...
The endothermic reactions of Mg^+ and Sr^+ with O_2 are studied in a guided ion beam mass spectromet...
The purpose of this kinetic study is to understand the non-Arrhenius behavior for the bimolecular re...
The selective oxidation of organic and inorganic substrates has gained much importance in recent yea...
The work presented in this thesis is concerned with the study of some small molecules by ultraviolet...
The Sm + O chemiionization reaction has been investigated theoretically using a method that allows f...
dissertationGuided ion beam mass spectrometry techniques are used to study the gas-phase ion-molecul...
The chemiluminescent reactions of ClO2 with Ca, Ba atoms have been studied under single collision co...
The U+O chemi-ionization reaction has been investigated by quantum chemical methods. Potential-energ...
Journal ArticleThe kinetic-energy dependence for the reactions of Con + (n=2-20) with O2 is measure...
peer reviewedDissociative ionization in O2 has been examined by means of a retarding potential lens ...
Equilibrium thermochemical analyses are employed to describe the vaporization processes of metals an...
1.Introduction. Electrons and metal ions in fluids play important roles in many aspects of chemlca...
The U+O chemi-ionization reaction has been investigated by quantum chemical methods. Potential-energ...
The Sm+O chemiionization reaction has been investigated theoretically using a method that allows for...
Most of this thesis is concerned with recording electron spectra arising either from photoionisation...
The endothermic reactions of Mg^+ and Sr^+ with O_2 are studied in a guided ion beam mass spectromet...
The purpose of this kinetic study is to understand the non-Arrhenius behavior for the bimolecular re...
The selective oxidation of organic and inorganic substrates has gained much importance in recent yea...
The work presented in this thesis is concerned with the study of some small molecules by ultraviolet...
The Sm + O chemiionization reaction has been investigated theoretically using a method that allows f...
dissertationGuided ion beam mass spectrometry techniques are used to study the gas-phase ion-molecul...
The chemiluminescent reactions of ClO2 with Ca, Ba atoms have been studied under single collision co...
The U+O chemi-ionization reaction has been investigated by quantum chemical methods. Potential-energ...
Journal ArticleThe kinetic-energy dependence for the reactions of Con + (n=2-20) with O2 is measure...
peer reviewedDissociative ionization in O2 has been examined by means of a retarding potential lens ...
Equilibrium thermochemical analyses are employed to describe the vaporization processes of metals an...
1.Introduction. Electrons and metal ions in fluids play important roles in many aspects of chemlca...