A flexible radical-based approach to tms-substituted propargyl alcohols and to 2,3-allenols

Li, Zhi
Zard, Samir, Z.

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Publication date

January 2009

DOI

10.1021/ol900739x

Publisher

American Chemical Society

Abstract

International audienceThe radical reaction of TMS-substituted xanthates with 2,2-dlchlorovlnyl ethyl sulfone afforded TMS-substltuted homodichlorovinyl compounds that can be transformed Into TMS-substituted propargyl alcohols. Various 2,3-allenols were efficiently prepared from the reaction of these TMS-substituted propargyl alcohols with TBAF. © 2009 American Chemical Society

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A flexible radical-based approach to tms-substituted propargyl alcohols and to 2,3-allenols

Abstract

Extracted data

A flexible radical-based approach to tms-substituted propargyl alcohols and to 2,3-allenols

Abstract

Extracted data

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