International audienceTwo pentamethylcyclopentadienyl (Cp*) rhodium(III) and iridium(III) metalla-prisms of the general formula [(Cp*M)6(tpt)2(dhnq)3]6+ (tpt = 2,4,6-tri-(pyridin-4-yl)-1,3,5-triazine, dhnq = 5,8-dihydroxy-1,4-naphthoquinonato; M = Rh, [1]6+; M = Ir, [2]6+) have been synthesized by mixing in methanol the neutral dinuclear complexes (Cp*M)2(dhnq)Cl2 (M = Rh, Ir), AgCF3SO3 and tpt. In a similar fashion, the addition of porphin during the formation of [1]6+ and [2]6+ leads to the carceplex systems [porphin⊂1]6+ and [porphin⊂2]6+. All complexes were isolated as their triflate salts and characterized by different analytical techniques including for the carceplex [porphin⊂1][CF3SO3]6 by a single-crystal X-ray structure analysis. T...
International audienceFour tetrapyridylporphyrin and four dipyridylporphyrin arene ruthenium complex...
AbstractHalf-sandwich organometallic rhodium and iridium complexes [1–6] have been synthesized with ...
A series of half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes [Cp*...
International audienceThree neutral dinuclear p-cymene ruthenium complexes (1a–1c) of the general fo...
Three neutral dinuclear <i>p</i>-cymene ruthenium complexes (<b>1a</b>–<b>1c</b>) of the general for...
Water-soluble metalla-cages were used to deliver hydrophobic porphin molecules to cancer cells. Afte...
Five 5,10,15,20-tetra(4-pyridyl)porphyrin (TPP) areneruthenium(II) derivs., a p-cymeneosmium, a pent...
Five 5,10,15,20-tetra(4-pyridyl)porphyrin (TPP) areneruthenium(II) derivatives and a p-cymeneosmium ...
A series of half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes [Cp*M(...
The synthesis and characterization of three [Rh(ppy)2(N^N)][PF6] complexes, [Rh(ppy)2(pybtz)][PF6].C...
The self-assembly of 2,4,6-tris(pyridin-4-yl)-1,3,5-triazine (tpt) triangular panels with p-cymene (...
Six new pentamethylcyclopentadienyl Rh(III) and Ir(III) metalla-rectangles ([3](CF3SO3)4–[8](CF3SO3)...
A series of half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes [Cp*M(...
Organometallic complexes play a key role in medicinal chemistry, especially in the development of an...
The present invention relates to novel organometallic compds. for use as a medicine, in particular i...
International audienceFour tetrapyridylporphyrin and four dipyridylporphyrin arene ruthenium complex...
AbstractHalf-sandwich organometallic rhodium and iridium complexes [1–6] have been synthesized with ...
A series of half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes [Cp*...
International audienceThree neutral dinuclear p-cymene ruthenium complexes (1a–1c) of the general fo...
Three neutral dinuclear <i>p</i>-cymene ruthenium complexes (<b>1a</b>–<b>1c</b>) of the general for...
Water-soluble metalla-cages were used to deliver hydrophobic porphin molecules to cancer cells. Afte...
Five 5,10,15,20-tetra(4-pyridyl)porphyrin (TPP) areneruthenium(II) derivs., a p-cymeneosmium, a pent...
Five 5,10,15,20-tetra(4-pyridyl)porphyrin (TPP) areneruthenium(II) derivatives and a p-cymeneosmium ...
A series of half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes [Cp*M(...
The synthesis and characterization of three [Rh(ppy)2(N^N)][PF6] complexes, [Rh(ppy)2(pybtz)][PF6].C...
The self-assembly of 2,4,6-tris(pyridin-4-yl)-1,3,5-triazine (tpt) triangular panels with p-cymene (...
Six new pentamethylcyclopentadienyl Rh(III) and Ir(III) metalla-rectangles ([3](CF3SO3)4–[8](CF3SO3)...
A series of half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes [Cp*M(...
Organometallic complexes play a key role in medicinal chemistry, especially in the development of an...
The present invention relates to novel organometallic compds. for use as a medicine, in particular i...
International audienceFour tetrapyridylporphyrin and four dipyridylporphyrin arene ruthenium complex...
AbstractHalf-sandwich organometallic rhodium and iridium complexes [1–6] have been synthesized with ...
A series of half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes [Cp*...