The reaction of nitric oxide (NO) on Cu(100) is studied by scanning tunneling microscopy, electron energy loss spectroscopy and density functional theory calculations. The NO molecules adsorb mainly as monomers at 64 K, and react and dissociate to yield oxygen atoms on the surface at ∼70 K. The temperature required for the dissociation is significantly low for Cu(100), compared to those for Cu(111) and Cu(110). The minimum energy pathway of the reaction is via (NO)₂ formation, which converts into a flat-lying ONNO and then dissociates into N₂O and O with a considerably low activation energy. We propose that the formation of (NO)₂ and flat-lying ONNO is the key to the exceptionally high reactivity of NO on Cu(100)
The interaction of NO with the O-rich RuO2(1 1 0) surface, exposing coordinatively unsaturated O-bri...
The interaction of NO with the stoichiometric RuO2(110) surface, exposing coordinatively unsaturated...
The interaction of NO with the stoichiometric RuO2(110) surface, exposing coordinatively unsaturated...
We investigate the adsorption and reaction of NO on Cu{311} via a combination of Reflection Absorpti...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The interaction of NO with Cu{110} is complex and is strongly dependent on both coverage and tempera...
We studied nitric oxide (NO) molecules on Cu(110) and Cu(001) surfaces with low-temperature scanning...
Density functional theory calculations here elucidated that Cu38-catalyzed NO reduction by CO occurr...
Density functional theory calculations here elucidated that Cu38-catalyzed NO reduction by CO occurr...
In a recent study [M. Feng, et al., ACS Nano, 2011, 5, 8877], it was shown that CO molecules adsorbe...
The interaction of NO with the O-rich RuO2(1 1 0) surface, exposing coordinatively unsaturated O-bri...
The interaction of NO with the O-rich RuO2(1 1 0) surface, exposing coordinatively unsaturated O-bri...
The interaction of NO with the stoichiometric RuO2(110) surface, exposing coordinatively unsaturated...
The interaction of NO with the stoichiometric RuO2(110) surface, exposing coordinatively unsaturated...
We investigate the adsorption and reaction of NO on Cu{311} via a combination of Reflection Absorpti...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The reactivity of the diatomic molecules O-2, N-2, CO and NO on Cu(100) has been studied on cluster ...
The interaction of NO with Cu{110} is complex and is strongly dependent on both coverage and tempera...
We studied nitric oxide (NO) molecules on Cu(110) and Cu(001) surfaces with low-temperature scanning...
Density functional theory calculations here elucidated that Cu38-catalyzed NO reduction by CO occurr...
Density functional theory calculations here elucidated that Cu38-catalyzed NO reduction by CO occurr...
In a recent study [M. Feng, et al., ACS Nano, 2011, 5, 8877], it was shown that CO molecules adsorbe...
The interaction of NO with the O-rich RuO2(1 1 0) surface, exposing coordinatively unsaturated O-bri...
The interaction of NO with the O-rich RuO2(1 1 0) surface, exposing coordinatively unsaturated O-bri...
The interaction of NO with the stoichiometric RuO2(110) surface, exposing coordinatively unsaturated...
The interaction of NO with the stoichiometric RuO2(110) surface, exposing coordinatively unsaturated...