40Ar/39Ar age evidence for an impact-generated hydrothermal system in the Devonian Siljan crater, Sweden

Crater-forming events are generally followed by the development of hydrothermal systems due to the rapid heating of the target rock. Such hydrothermal systems are a feature of nearly all large terrestrial impact structures. For the Siljan impact structure in Sweden, there is evidence for such a fossil hydrothermal system, possibly triggered by the impact event ca. 380 Ma. To investigate the thermal regime of the near-surface hydrothermal activity of the Siljan crater, biotite and amphibole grains extracted from samples collected in a transect across the high-pressure regime recorded by the central uplift, as well as from distal localities outside the central uplift of the crater, were dated using the 40Ar/39Ar laser step-heating technique. Our results show that biotite from inside the central uplift, which was strongly altered to chlorite by low-temperature (200-340°C) hydrothermal reactions, yields strongly disturbed age spectra. The first and second (low laser power) step ages range from ca. 1300 to 190 Ma. In contrast, biotite from outside the central uplift and amphibole, irrespective of location inside or outside of the central uplift, are much less altered, which is reflected in less disturbed, near-flat age spectra. This result indicates that the hydrothermal temperatures inside the central uplift were >200°C, sufficient to disturb the K-Ar system of biotite during its chloritization, but too low to affect the amphibole (closure temperature of 480-580°C). In contrast, the temperature of the hydrothermal system outside of the central uplift was