Wireless communication systems can be optimised through more accurate radio modelling processes. Ray-tracing methods, based on geometrical optics (GO) and the uniform theory of diffraction (UTD), have emerged as the preferred technique to predict the electric field distribution and area coverage in both indoor and outdoor environments. There have been a number of investigations on improving the accuracy of ray-tracing methods in both indoor and outdoor environments, but few pay attention to the inner structure of the walls. In existing ray- tracing algorithms, wall structures are usually modelled as half-space materials or dielectric slab and layered models, with reflection and transmission characteristics calculated by Fresnel coefficients...