Topic « Lasers, Optics, and Optoelectronics »International audienceWe report the fabrication and the physical and optical characterizations of sulphide GaxGe25−xSb10S65(x=0,5) rib waveguides. High quality films fabricated on SiO2/Si wafer substrates were obtained using the sputtering magnetron rf deposition method. The slab waveguides obtained without annealing present propagation losses of about 0.6 dB/cm at 1550 nm. These optical losses are not important for implementation in optical devices based on silicon-on-insulator or polymer, for instance, atomic force microscopy measurements revealed low interface roughness between the different media (substrate/film and film/air). Reactive ion etching was used to pattern rib waveguides between 2 ...