Quantum groups first arose out of the study of integrability in quantum mechanics, presenting a new notion of symmetry extending beyond the traditional group concept. Quantum groups can be thought of as the collection of symmetries of noncommutative spaces, which arise in many areas of modern physics and mathematics. This thesis deals with two topics in the theory of (operator algebraic) quantum groups. On the one hand, we study the von Neumann algebras of certain Kac type compact quantum groups. This well-behaved class is amenable to methods from free probability to study their fine analytic structure. We establish several important properties, such as Connes embeddability and strong 1-boundedness, in a number of examples of these quantum ...