International audiencePrestellar cores are unique laboratories for studying the chemical and physical conditions preceding star formation. We observed the prestellar core L1544 in the fundamental transition of ortho-H2D+ (11,0-11,1) at different positions over 100" and found a strong correlation between its abundance and the CO depletion factor. We also present a tentative detection of the fundamental transition of para-D2H+ (11,0-10,1) at the dust emission peak. Maps in N2H+, N2D+, HCO+, and DCO+ are used and interpreted with the aid of a spherically symmetric chemical model that predicts the column densities and abundances of these species as a function of radius. The correlation between the observed deuterium fractionation of H+3, N2H+, ...