International audienceTreatment of LnACHTUNGTRENUNG(NO3)3*nH2O with 1 or 2 equiv 2,2'-bipyrimidine (BPM) in dry THF readily afforded the monometallic complexes [LnACHTUNGTRENUNG(NO3)3- ACHTUNGTRENUNG(bpm)2] (Ln=Eu, Gd, Dy, Tm) or [Ln- ACHTUNGTRENUNG(NO3)3ACHTUNGTRENUNG(bpm)2]*THF (Ln=Eu, Tb, Er, Yb) after recrystallization from MeOH or THF, respectively. Reactions with nitrate salts of the larger lanthanide ions (Ln=Ce, Nd, Sm) yielded one of two distinct monometallic complexes, depending on the recrystallization solvent: [LnACHTUNGTRENUNG(NO3)3ACHTUNGTRENUNG(bpm)2]*THF (Ln=Nd, Sm) from THF, or [LnACHTUNGTRENUNG(NO3)3ACHTUNGTRENUNG(bpm)- ACHTUNGTRENUNG(MeOH)2]*MeOH (Ln=Ce, Nd, Sm) from MeOH. Treatment of UO2- ACHTUNGTRENUNG(NO3)2*6H2O with ...
Reaction of the cyanoruthenate anions [Ru(bpym)(CN)4]2- and [[Ru(CN)4]2(mu-bpym)]4- (bpym = 2,2'-bip...
Reaction of the cyanoruthenate anions [Ru(bpym)(CN)4]2- and [{Ru(CN)4}2(μ-bpym)]4- (bpym = 2,2‘-bipy...
International audienceLanthanide complexes Ln(L1)(HL1) (Ln = Lu, Yb, Er, Gd, Eu, Sm) and Ln(L2)(HL2)...
International audienceTreatment of LnACHTUNGTRENUNG(NO3)3*nH2O with 1 or 2 equiv 2,2'-bipyrimidine (...
Bipyrimidines have been chosen as ((NN)-N-boolean AND)((NN)-N-boolean AND) bridging ligands for conn...
International audienceTreatment of Nd(NO3)3 with 2,2′-bipyrimidine (bpm) afforded the mononuclear ad...
Despite the strong technological importance of lanthanide complexes, their formation processes are r...
The synthesis, solution behavior and photophysical properties of several heteronuclear bimetallic d/...
International audienceWith the help of associations between Eu3+, Yb3+, and Nd3+ ions and low-potent...
Reaction of the cyanoruthenate anions [Ru(bpym)(CN)4]2- and [[Ru(CN)4]2(mu-bpym)]4- (bpym = 2,2'-bip...
Reaction of the cyanoruthenate anions [Ru(bpym)(CN)4]2- and [{Ru(CN)4}2(μ-bpym)]4- (bpym = 2,2‘-bipy...
International audienceLanthanide complexes Ln(L1)(HL1) (Ln = Lu, Yb, Er, Gd, Eu, Sm) and Ln(L2)(HL2)...
International audienceTreatment of LnACHTUNGTRENUNG(NO3)3*nH2O with 1 or 2 equiv 2,2'-bipyrimidine (...
Bipyrimidines have been chosen as ((NN)-N-boolean AND)((NN)-N-boolean AND) bridging ligands for conn...
International audienceTreatment of Nd(NO3)3 with 2,2′-bipyrimidine (bpm) afforded the mononuclear ad...
Despite the strong technological importance of lanthanide complexes, their formation processes are r...
The synthesis, solution behavior and photophysical properties of several heteronuclear bimetallic d/...
International audienceWith the help of associations between Eu3+, Yb3+, and Nd3+ ions and low-potent...
Reaction of the cyanoruthenate anions [Ru(bpym)(CN)4]2- and [[Ru(CN)4]2(mu-bpym)]4- (bpym = 2,2'-bip...
Reaction of the cyanoruthenate anions [Ru(bpym)(CN)4]2- and [{Ru(CN)4}2(μ-bpym)]4- (bpym = 2,2‘-bipy...
International audienceLanthanide complexes Ln(L1)(HL1) (Ln = Lu, Yb, Er, Gd, Eu, Sm) and Ln(L2)(HL2)...