Catalytic hydrogen production by a Ni-Ru mimic of NiFe hydrogenases involves a proton-coupled electron transfer step.
- Canaguier, Sigolène
- Fourmond, Vincent
- Perotto, Carlo U
- Fize, Jennifer
- Pécaut, Jacques
- Fontecave, Marc
- Field, Martin J
- Artero, Vincent
DOIAbstract
International audienceA combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases [Ni(xbsms)Ru(C6Me6)Cl](+) proceeds through proton-coupled electron transfer steps
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