Lipase catalysed oxidations in a sugar-derived natural deep eutectic solvent
- Vagnoni M.
- Samori' C.
- Pirini D.
- Vasquez De Paz M. K.
- Gidey D. G.
- Galletti P.
DOIAbstract
Chemoenzymatic oxidations involving the CAL-B/H2O2 system was developed in a sugar derived Natural Deep Eutectic Solvent (NaDES) composed by a mixture of glucose, fructose and sucrose. Good to excellent conversions of substrates like cyclooctene, limonene, oleic acid and stilbene to their corresponding epoxides, cyclohexanone to its corresponding lactone and 2-phenylacetophenone to its corresponding ester, demonstrate the viability of the sugar NaDES as a reaction medium for epoxidation and Baeyer-Villiger oxidation
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