Urban Built Environments (UBE) are increasingly prone to SLow‐Onset Disasters (SLODs) such as air pollution and heatwaves. The effectiveness of sustainable risk‐mitigation solutions for the exposed individuals’ health should be defined by considering the effective scenarios in which emergency conditions can appear. Combining environmental (including climatic) conditions and exposed users’ presence and behaviors is a paramount task to support decision‐makers in risk assessment. A clear definition of input scenarios and related critical conditions to be analyzed is needed, especially while applying simulation‐based approaches. This work provides a methodology to fill this gap, based on hazard and exposure peaks identification. Quick and remot...