The synthesis and properties of silanes bearing a bulky carbazolyl substituent are described. Metathesis routes with different reagents under different conditions are required to obtain the compounds of the general formula RSi(X)$_{2}$H and RSi(X)$_{2}$All (X=Cl, N$_{3}$, NCO, NCS, NH$_{2}$, All=CH$_{2}$CHCH$_{2}$). The silanes were studied by XRD, NMR and IR spectroscopy and all findings were corroborated by DFT methods
Despite the attractive optical and electronic properties of oligosilanes and polysilanes, the develo...
Unless kinetically stabilized, hydroxides of silicon are unstable and readily self-condense through ...
A study has been carried out on the preparation of some organofunctional imido silanes. This has be...
The reaction of an α-trialkylsilylvinyl carbanion and carboxylic acid derivatives gives α,β-unsatura...
Silicon nanomaterials combine earth abundance and biodegradability with compelling electronic proper...
Work carried in the authors laboratory on Si–CH 2 –Si bridged polycarbosilanes is reviewed. In pursu...
Organosilanols typically show a high condensation tendency and only exist as stable isolable molecul...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
Organosilicon compounds exhibit a multitude of functions in organic synthesis, therefore a plenty of...
Organosilicon compounds exhibit a multitude of functions in organic synthesis, therefore a plenty of...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
none2Organosilicon compounds exhibit a multitude of functions in organic synthesis, therefore a plen...
Our interest in organosilicon compounds has led us to examine the chemistry of rarely used α-silylca...
Siloxanes have evolved into a multi-million dollar business due to their manifold of commercial and ...
A study was carried out on the preparation of triethoxy-silyl derivatives of the allyl esters of se...
Despite the attractive optical and electronic properties of oligosilanes and polysilanes, the develo...
Unless kinetically stabilized, hydroxides of silicon are unstable and readily self-condense through ...
A study has been carried out on the preparation of some organofunctional imido silanes. This has be...
The reaction of an α-trialkylsilylvinyl carbanion and carboxylic acid derivatives gives α,β-unsatura...
Silicon nanomaterials combine earth abundance and biodegradability with compelling electronic proper...
Work carried in the authors laboratory on Si–CH 2 –Si bridged polycarbosilanes is reviewed. In pursu...
Organosilanols typically show a high condensation tendency and only exist as stable isolable molecul...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
Organosilicon compounds exhibit a multitude of functions in organic synthesis, therefore a plenty of...
Organosilicon compounds exhibit a multitude of functions in organic synthesis, therefore a plenty of...
Herein, we report new allylation reactions using ring-strained allylalkoxysiletanes. These reactions...
none2Organosilicon compounds exhibit a multitude of functions in organic synthesis, therefore a plen...
Our interest in organosilicon compounds has led us to examine the chemistry of rarely used α-silylca...
Siloxanes have evolved into a multi-million dollar business due to their manifold of commercial and ...
A study was carried out on the preparation of triethoxy-silyl derivatives of the allyl esters of se...
Despite the attractive optical and electronic properties of oligosilanes and polysilanes, the develo...
Unless kinetically stabilized, hydroxides of silicon are unstable and readily self-condense through ...
A study has been carried out on the preparation of some organofunctional imido silanes. This has be...
DOI
Add to ORKG