International audienceThe size distribution of polycyclic aromatic hydrocarbons (PAHs) and PAH derivatives was determined during the intensive sampling campaigns of the POVA (Pollution des Vallées Alpines) research programme, in two French alpine valleys, in winter and summer. The size distributions of PAHs, oxygenated PAHs (OPAHs) and nitrated PAHs (NPAHs) present large variations with year time and site type (traffic; suburban and rural). In general, these compounds were mainly associated (60-90%) with fine particles (Dp<1.3 μm) in agreement with their release from sources (primary and/or secondary). The pollutant distributions with particle size were unimodal and centred at 0.85 μm both in the Chamonix and Maurienne valleys. The summer s...