Codata thermodynamic tables : the alloy system Ca-Mg

International audienceRecommended values are presented for chemical thermodynamic properties of selected compounds of calcium and their mixtures. These have been prepared in accord with a previously developed plan and as a test of it. All values in the present table are mutually consistent and are consistent with the CODATA Key Values for Thermodynamics. The values are recommended for general use. This work has been an activity of the CODATA Task Group on Chemical Thermodynamic Tables. The evaluated data are for common compounds of calcium (element, oxide, hydroxide, peroxide, fluoride, sulfate, nitrate and carbonate, their hydrates and their ions in aqueous solution) and for three systems: Ca-Mg, CaCl/sub 2/-KCl and CaCl/sub 2/-H/sub 2/O. Forty one tables of thermal functions (heat capacity, entropy, enthalpy, and Gibbs energy functions) are given for those compounds of magnesium, calcium and potassium for which the properties have been evaluated in this work. Twenty four tables of thermal functions are given for auxiliary substances. Each table spans the temperature range 0 to 4000 K, to the extent that data are available. Formation properties at 298.15 K (enthalpy and Gibbs energy of formation) are given for 68 compounds of calcium, magnesium and potassium plus the relevant values for 54 auxiliary substances