The reaction of (C5Me5)Hf(s-cis-C6H10)Cl with benzophenone results in sequential insertion of two ketone molecules in the Hf-diene bond through adduct intermediates. The final 1,3-dioxa-2-hafnacyclonon-6-ene has a cis-configuration around the double bond, in contrast with related products from (C5H5)2Zr(diene)
This thesis describes attempts to use palladium-catalysed cross-coupling methodology in the synthesi...
Cycloadditions of various 1,3-dipolar reagents to chiral butenolides 1 and 5 proceed with diastereom...
Reaction of decamethylmetallocene cations [Cp-2*M](+) (M = Sc, Ti, V) with acetone and benzophenone ...
The reaction of (C5Me5)Hf(s-cis-C6H10)Cl with benzophenone results in sequential insertion of two ke...
The reaction of (C5Me5) Hf (s-cis-C6H10)Cl with benzophenone results in sequential insertion of two ...
A group of electronically unsaturated (14-electron) diene complexes of Hf and Ti has been reacted wi...
Open access: Despite the exceptional level of sophistication in cross-coupling chemistry, reactions ...
Diphenylketene (2) undergoes [4 + 2] cycloadditions with the s-cis fixed diene (1) to give the dihyd...
Diene 2b reacted regioselectively with dienophiles. Adduct 6 was converted into the left-hand portio...
Decamethylzirconocene cation [Cp*2ZrMe](+) (2) decomposes in bromobenzene-d(5) solution to generate ...
Hexachlorocyclopentadiene and related compounds have been studied extensively in connection with Die...
At the beginning of the reseach described in this thesis the catalytic asymmetric Diels-Alder reacti...
This thesis describes attempts to use palladium-catalysed cross-coupling methodology in the synthesi...
Cycloadditions of various 1,3-dipolar reagents to chiral butenolides 1 and 5 proceed with diastereom...
Reaction of decamethylmetallocene cations [Cp-2*M](+) (M = Sc, Ti, V) with acetone and benzophenone ...
The reaction of (C5Me5)Hf(s-cis-C6H10)Cl with benzophenone results in sequential insertion of two ke...
The reaction of (C5Me5) Hf (s-cis-C6H10)Cl with benzophenone results in sequential insertion of two ...
A group of electronically unsaturated (14-electron) diene complexes of Hf and Ti has been reacted wi...
Open access: Despite the exceptional level of sophistication in cross-coupling chemistry, reactions ...
Diphenylketene (2) undergoes [4 + 2] cycloadditions with the s-cis fixed diene (1) to give the dihyd...
Diene 2b reacted regioselectively with dienophiles. Adduct 6 was converted into the left-hand portio...
Decamethylzirconocene cation [Cp*2ZrMe](+) (2) decomposes in bromobenzene-d(5) solution to generate ...
Hexachlorocyclopentadiene and related compounds have been studied extensively in connection with Die...
At the beginning of the reseach described in this thesis the catalytic asymmetric Diels-Alder reacti...
This thesis describes attempts to use palladium-catalysed cross-coupling methodology in the synthesi...
Cycloadditions of various 1,3-dipolar reagents to chiral butenolides 1 and 5 proceed with diastereom...
Reaction of decamethylmetallocene cations [Cp-2*M](+) (M = Sc, Ti, V) with acetone and benzophenone ...