We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alcohol (TBA), trimethyl-amine-oxide (TMAO), and tetramethylurea (TMU) in isotopically diluted water (HDO:D(2)O and HDO:H(2)O). The spectral dynamics are studied with femtosecond two-dimensional infrared spectroscopy and the orientational dynamics with femtosecond polarization-resolved vibrational pump probe spectroscopy. We observe a strong slowing down of the spectral diffusion around the central part of the absorption line that increases with increasing solute concentration. At low concentrations, the fraction of water showing slow spectral dynamics is observed to scale with the number of methyl groups, indicating that this effect is due to sl...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiary-butyl-alc...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiary-butyl-alc...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in solutions of tertiarybutyl-alco...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
We study the spectral and orientational dynamics of HDO molecules in aqueous solutions of different ...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...
For decades, the enigma of the hydrophobic force has captured the imagination of scientists. in part...