The synthesis of novel hydrocarbyl and hydride cerium complexes Cp*2CeCH(SiMe3)2 (Cp* = η5-C5Me5) and (Cp*2CeH)2 is reported. The hydrocarbyl shows Lewis acid properties and complexes salts like LiCl. The hydride is exceptionally reactive and activates P-C bonds in PMe3
Protolysis of the cerium alkyl Cp*2CeCH(SiMe3)2 (1) by triethylammoniumtetraphenylborate provides a ...
Tris(2,6-di-t-butylphenoxo)cerium reacts with (C5Me5)Li in pentane to form (η5-C5Me5)bis(2,6-di-t-bu...
A reaction sequence involving two hydrogen transfers and a C-C coupling on the β-carbon of an isopro...
The synthesis of novel hydrocarbyl and hydride cerium complexes Cp*2CeCH(SiMe3)2 (Cp* = η5-C5Me5) an...
A convenient three step synthesis of (Cp*2YH)n (Cp* = C5Me5) is described starting with YCl3.3thf, i...
Thermolysis of complexes Cp*2LnCH(SiMe3)2 (1, Ln = Y; 2, Ln = La; 3, Ln = Ce) in cyclohexane leads t...
This Tutorial Review provides an overview of the historic and current development of the organometal...
CeCl3.xTHF (1 < x < 2) reacts with 2 equiv of Cp*Li in THF forming Cp*2CeCl2Li(THF)2.5 (1). The coor...
Paramagnetic high-spin d2 and d3 monocyclopentadienyl vanadium hydrocarbyl complexes CpVIII2(PMe3)2 ...
Protolysis of the cerium alkyl Cp*2CeCH(SiMe3)2 (1) by triethylammoniumtetraphenylborate provides a ...
Tris(2,6-di-t-butylphenoxo)cerium reacts with (C5Me5)Li in pentane to form (η5-C5Me5)bis(2,6-di-t-bu...
A reaction sequence involving two hydrogen transfers and a C-C coupling on the β-carbon of an isopro...
The synthesis of novel hydrocarbyl and hydride cerium complexes Cp*2CeCH(SiMe3)2 (Cp* = η5-C5Me5) an...
A convenient three step synthesis of (Cp*2YH)n (Cp* = C5Me5) is described starting with YCl3.3thf, i...
Thermolysis of complexes Cp*2LnCH(SiMe3)2 (1, Ln = Y; 2, Ln = La; 3, Ln = Ce) in cyclohexane leads t...
This Tutorial Review provides an overview of the historic and current development of the organometal...
CeCl3.xTHF (1 < x < 2) reacts with 2 equiv of Cp*Li in THF forming Cp*2CeCl2Li(THF)2.5 (1). The coor...
Paramagnetic high-spin d2 and d3 monocyclopentadienyl vanadium hydrocarbyl complexes CpVIII2(PMe3)2 ...
Protolysis of the cerium alkyl Cp*2CeCH(SiMe3)2 (1) by triethylammoniumtetraphenylborate provides a ...
Tris(2,6-di-t-butylphenoxo)cerium reacts with (C5Me5)Li in pentane to form (η5-C5Me5)bis(2,6-di-t-bu...
A reaction sequence involving two hydrogen transfers and a C-C coupling on the β-carbon of an isopro...