Korte beschrijving: Since the discovery of olefin polymerization catalysts based on titanium and aluminum by Ziegler, polyolefins have grown to become one of the most important group of plastics. Millions of tons of polyolefins are produced every year, and the production is still expanding. Soluble single-site catalysts, that were once used as simple models for the heterogeneous Ziegler catalysts, have now developed in to a new and independent group of catalysts. Zie: Samenvatting and Summar
Cationic monocyclopentadienyl (half-sandwich) titanium complexes are especially known as catalysts f...
Thermolysis of half-sandwich vanadium imido complexes Cp(RN)V(i-Pr(2)N)Me (R = p-Tol, 1a; R = t-Bu, ...
The goal of the research discussed in this paper is to demonstrate that N-heterocyclic carbenes can ...
Korte beschrijving: Since the discovery of olefin polymerization catalysts based on titanium and alu...
The (N,N-dimethylaminoethyl)cyclopentadienyI vanadium(III) complex [eta(5),eta(1)-C5H4(CH2)(2)-NMe2]...
Many important industrial processes make use of catalyzed reactions. One of the best known catalytic...
Although olefin complexes of the early transition metals are frequently named as intermediates in ca...
Reduction of the V(III) (beta-(dimethylamino)ethyl)cyclopentadienyl dichloride complex [eta(5):eta(1...
Reduction of CpVX2(PR3)2 (X = Cl, R = Me, Et; X = Br, R = Et) with Al or Zn in THF gives dimeric van...
De organometaalchemie en vooral die van overgangsmetalen en lanthaniden heeft zich in 40-50 jaar bui...
One of the trimethylphosphine ligands in CpV(NAr)(PMe3)2 (3; Ar = 2,6-C6H3-i-Pr2), obtained by magne...
The design and synthesis of well-defined vanadium complexes as efficient catalysts for olefin polyme...
A series of V(III) catalysts with different substituted 1,3-dionates $\rm(V(acac)\sb3$ 2.1, V(Cy-$\r...
International audienceReaction of {2,6-bis[2,6-(i-Pr)2PhNC(Me)]2(C5H3N)}VCl3·1.3(CH2Cl2) (1) with st...
Cationic monocyclopentadienyl (half-sandwich) titanium complexes are especially known as catalysts f...
Thermolysis of half-sandwich vanadium imido complexes Cp(RN)V(i-Pr(2)N)Me (R = p-Tol, 1a; R = t-Bu, ...
The goal of the research discussed in this paper is to demonstrate that N-heterocyclic carbenes can ...
Korte beschrijving: Since the discovery of olefin polymerization catalysts based on titanium and alu...
The (N,N-dimethylaminoethyl)cyclopentadienyI vanadium(III) complex [eta(5),eta(1)-C5H4(CH2)(2)-NMe2]...
Many important industrial processes make use of catalyzed reactions. One of the best known catalytic...
Although olefin complexes of the early transition metals are frequently named as intermediates in ca...
Reduction of the V(III) (beta-(dimethylamino)ethyl)cyclopentadienyl dichloride complex [eta(5):eta(1...
Reduction of CpVX2(PR3)2 (X = Cl, R = Me, Et; X = Br, R = Et) with Al or Zn in THF gives dimeric van...
De organometaalchemie en vooral die van overgangsmetalen en lanthaniden heeft zich in 40-50 jaar bui...
One of the trimethylphosphine ligands in CpV(NAr)(PMe3)2 (3; Ar = 2,6-C6H3-i-Pr2), obtained by magne...
The design and synthesis of well-defined vanadium complexes as efficient catalysts for olefin polyme...
A series of V(III) catalysts with different substituted 1,3-dionates $\rm(V(acac)\sb3$ 2.1, V(Cy-$\r...
International audienceReaction of {2,6-bis[2,6-(i-Pr)2PhNC(Me)]2(C5H3N)}VCl3·1.3(CH2Cl2) (1) with st...
Cationic monocyclopentadienyl (half-sandwich) titanium complexes are especially known as catalysts f...
Thermolysis of half-sandwich vanadium imido complexes Cp(RN)V(i-Pr(2)N)Me (R = p-Tol, 1a; R = t-Bu, ...
The goal of the research discussed in this paper is to demonstrate that N-heterocyclic carbenes can ...