Add to ORKGSpecific conformations of molecules may be induced by the solvent when a large free volume is associated with the oonformational change. The conformational energy barrier is then a property of the solvent, rather than of the molecule. Such effects are reported for several substituted phenyl-benzyl-nitroxides, where Solvent Induced Conformational Kinetics ( SICK) can be studied by ESR.</p
An investigation into the modes of interaction and mechanisms of proton relaxation enhancement of th...
1. By means of NMR, experimental data have been obtained on the dependence of conformational equilib...
A new approach to determination of partial rate constants for reactions of conformers is developed o...
Specific conformations of molecules may be induced by the solvent when a large free volume is associ...
For geminally diphosphorylated linear nitroxide radicals, a marked line width alternation (LWA) can ...
The three dimensional structure of a protein is important for its function. When misfolded, a protei...
For geminally diphosphorylated linear nitroxide radicals, a marked line width alternation (LWA) can ...
The thiol-ene reaction is one of the fundamental reactions in biochemistry and synthetic organic che...
Steric effects of nitroaromatic radical anions have been studied utilizing esr spectroscopy. We have...
tio th gh otheir rate coefficients one needs to develop models providing the link between macroscopi...
Enantiomeric excess (ee) in asymmetric catalysis may be strongly dependent on the solvent. The react...
An ESR study of interactions between the nonmesomorphic nitroxide spin probe solutes PD-tempone (PDT...
From an analysis of the variation of1 H NMR spectra with temperature it has been shown that 2-substi...
The conformational distribution of methyl phenyl sulfoxide (a molecule representative of a very impo...
Of the factors that may govern the rate of a homogeneous chemical reaction in solution, probably the...
An investigation into the modes of interaction and mechanisms of proton relaxation enhancement of th...
1. By means of NMR, experimental data have been obtained on the dependence of conformational equilib...
A new approach to determination of partial rate constants for reactions of conformers is developed o...
Specific conformations of molecules may be induced by the solvent when a large free volume is associ...
For geminally diphosphorylated linear nitroxide radicals, a marked line width alternation (LWA) can ...
The three dimensional structure of a protein is important for its function. When misfolded, a protei...
For geminally diphosphorylated linear nitroxide radicals, a marked line width alternation (LWA) can ...
The thiol-ene reaction is one of the fundamental reactions in biochemistry and synthetic organic che...
Steric effects of nitroaromatic radical anions have been studied utilizing esr spectroscopy. We have...
tio th gh otheir rate coefficients one needs to develop models providing the link between macroscopi...
Enantiomeric excess (ee) in asymmetric catalysis may be strongly dependent on the solvent. The react...
An ESR study of interactions between the nonmesomorphic nitroxide spin probe solutes PD-tempone (PDT...
From an analysis of the variation of1 H NMR spectra with temperature it has been shown that 2-substi...
The conformational distribution of methyl phenyl sulfoxide (a molecule representative of a very impo...
Of the factors that may govern the rate of a homogeneous chemical reaction in solution, probably the...
An investigation into the modes of interaction and mechanisms of proton relaxation enhancement of th...
1. By means of NMR, experimental data have been obtained on the dependence of conformational equilib...
A new approach to determination of partial rate constants for reactions of conformers is developed o...