Reaction of YCl3 . 3.5THF with Cp*K followed by [PhC(NSiMe(3))(2)]Li . OEt(2) in THF gives the surprisingly stable yttrium cyclopentadienyl-benzamidinate chloride {Cp*[PhC(NSiMe(3))(2)]Y(mu-Cl)}(2) (1). Thermally induced redistribution of the various ligands leading to disproportionation of the molecule was not observed. The dimer does not split easily, e.g., it does not react with THF to give Cp*[PhC(NSiMe(3))(2)]YCl . THF. Attempts to produce monomeric derivatives of 1 by substitution of the chloride by alkoxy, amide, or alkyl substituents using salt metathesis methodology were not successful. Reaction of 1 with 2 equiv of MeLi in the presence of TMEDA (TMEDA = N,N,N',N'-tetramethylethylenediamine) afforded the structurally characterized ...
The synthesis of [PhC(NSiMe(3))(2)]Y-2(mu-Cl)(2)Li . 2THF (1) from YCl3 . 3.5THF and [PhC(NSiMe(3))(...
1,4,6-Trimethyl-N-(2-pyrrolidin-1-ylethyl)-1,4-diazepan-6-amine (HL) reacts with M(CH(2)Ph)(3)(THF)(...
Simple tribenzyl complexes of lanthanum, [La(CH2C6H4-4-R)(3)(THF)(3)] (R = H (1a), Me (1b)), were pr...
Reaction of YCl3 . 3.5THF with Cp*K followed by [PhC(NSiMe(3))(2)]Li . OEt(2) in THF gives the surpr...
Reaction of YCl3·3.5THF with Cp*K followed by [PhC(NSiMe3)2]Li·OEt2 in THF gives the surprisingly st...
Treatment of C5H4CH2CH2OMe · Li(TMEDA) (TMEDA = N, N, N´, N´ tetramethylethylenediamine) with half a...
Reaction of YCl3·THF3.5 with 2 equiv of [Me2Si(NCMe3)(OCMe3)]Li produces [Me2Si(NCMe3)(OCMe3)]2Y(μ-C...
Reaction of YCl3 . THF3.5 with 2 equiv of [Me2Si(NCMe3)(OCMe3)]Li produces [Me2Si(NCMe3)(OCMe3)](2)Y...
Reaction of YCl3 . THF3.5 with 2 equiv of [Me2Si(NCMe3)(OCMe3)]Li produces [Me2Si(NCMe3)(OCMe3)](2)Y...
The reactivity of benzamidinate-stabilized yttrium complexes [PhC(NSiMe3)2]2YR (R = CH2Ph·THF, CH(Si...
The synthesis of [PhC(NSiMe(3))(2)]Y-2(mu-Cl)(2)Li . 2THF (1) from YCl3 . 3.5THF and [PhC(NSiMe(3))(...
The synthesis of [PhC(NSiMe(3))(2)]Y-2(mu-Cl)(2)Li . 2THF (1) from YCl3 . 3.5THF and [PhC(NSiMe(3))(...
1,4,6-Trimethyl-N-(2-pyrrolidin-1-ylethyl)-1,4-diazepan-6-amine (HL) reacts with M(CH(2)Ph)(3)(THF)(...
Simple tribenzyl complexes of lanthanum, [La(CH2C6H4-4-R)(3)(THF)(3)] (R = H (1a), Me (1b)), were pr...
Reaction of YCl3 . 3.5THF with Cp*K followed by [PhC(NSiMe(3))(2)]Li . OEt(2) in THF gives the surpr...
Reaction of YCl3·3.5THF with Cp*K followed by [PhC(NSiMe3)2]Li·OEt2 in THF gives the surprisingly st...
Treatment of C5H4CH2CH2OMe · Li(TMEDA) (TMEDA = N, N, N´, N´ tetramethylethylenediamine) with half a...
Reaction of YCl3·THF3.5 with 2 equiv of [Me2Si(NCMe3)(OCMe3)]Li produces [Me2Si(NCMe3)(OCMe3)]2Y(μ-C...
Reaction of YCl3 . THF3.5 with 2 equiv of [Me2Si(NCMe3)(OCMe3)]Li produces [Me2Si(NCMe3)(OCMe3)](2)Y...
Reaction of YCl3 . THF3.5 with 2 equiv of [Me2Si(NCMe3)(OCMe3)]Li produces [Me2Si(NCMe3)(OCMe3)](2)Y...
The reactivity of benzamidinate-stabilized yttrium complexes [PhC(NSiMe3)2]2YR (R = CH2Ph·THF, CH(Si...
The synthesis of [PhC(NSiMe(3))(2)]Y-2(mu-Cl)(2)Li . 2THF (1) from YCl3 . 3.5THF and [PhC(NSiMe(3))(...
The synthesis of [PhC(NSiMe(3))(2)]Y-2(mu-Cl)(2)Li . 2THF (1) from YCl3 . 3.5THF and [PhC(NSiMe(3))(...
1,4,6-Trimethyl-N-(2-pyrrolidin-1-ylethyl)-1,4-diazepan-6-amine (HL) reacts with M(CH(2)Ph)(3)(THF)(...
Simple tribenzyl complexes of lanthanum, [La(CH2C6H4-4-R)(3)(THF)(3)] (R = H (1a), Me (1b)), were pr...