An invention of new catalytic strategies for stereoselective synthesis is of current interest to many laboratories worldwide . Over the past few decades a remark - able progress in the field of stereocontrolled synthesis has been achieved with chiral 1,1’-binaphthyl compounds. Optically active 1,1’-binaphthyl-2,2’-diol (BINOL) and its derivatives due to their axial dissymmetry and molecular flexibility have been widely utilized as chiral ligands and auxiliaries in stoichiometric or catalytic asymmetric reactions, such as metal-catalysed transformations and enantioselective organocatalysis. BINOL and its functionalized analogues have demonstrated remark - able chiral discrimination properties. Extensive studies on molecular recognition ...
Pierwsza reakcja sprzęgania pierścieni arylowych katalizowanego miedzią została przeprowadzona przez...
Axially chiral biaryls, as exemplified by 1,1’-bi-2-naphthol (BINOL), are key components of catalyst...
Condensations of aromatic aldehydes with 2,2′-diamino-1,1′ -binaphthyl or 2-amino-2′-hydroxy-1,1′-bi...
1,1’-Binaphthyl and its derivatives represent a particular class of chemical molecules which chirali...
Synthesis of enantiomerically pure compounds by the use of “man made” chiral inducers has the greate...
8 1 INTRODUCTION Over the last two decades, high-performance liquid chromatography (HPLC) has become...
The use of 7-deoxycholic acid as a chiral template in the asymmetric syntheses of 1,1'-binaphthyl-2,...
The use of chiral counterions to facilitate enantioselective mono-C-alkylation of enolates has been...
3,3'-Bis(dialkylaminomethyl)-1,1'-binaphth-2-ols (Binolams) have emerged during the last five years ...
The use of 7-deoxycholic acid as a chiral template in the asymmetric syntheses of 1,1'-binaphthyl-2,...
Organocatalysis has emerged as a powerful synthetic tool in organic chemistry in the last few decade...
The efforts described in this dissertation initially focus on the asymmetric synthesis of axially ch...
The efforts described in this dissertation initially focus on the asymmetric synthesis of axially ch...
Herein we disclose a scalable organocatalytic direct arylation approach for the regio- and atroposel...
The lithiation, of the secondary chloride 2, catalyzed by binaphthyl derivatives, i.e. BINAM 4, BINO...
Pierwsza reakcja sprzęgania pierścieni arylowych katalizowanego miedzią została przeprowadzona przez...
Axially chiral biaryls, as exemplified by 1,1’-bi-2-naphthol (BINOL), are key components of catalyst...
Condensations of aromatic aldehydes with 2,2′-diamino-1,1′ -binaphthyl or 2-amino-2′-hydroxy-1,1′-bi...
1,1’-Binaphthyl and its derivatives represent a particular class of chemical molecules which chirali...
Synthesis of enantiomerically pure compounds by the use of “man made” chiral inducers has the greate...
8 1 INTRODUCTION Over the last two decades, high-performance liquid chromatography (HPLC) has become...
The use of 7-deoxycholic acid as a chiral template in the asymmetric syntheses of 1,1'-binaphthyl-2,...
The use of chiral counterions to facilitate enantioselective mono-C-alkylation of enolates has been...
3,3'-Bis(dialkylaminomethyl)-1,1'-binaphth-2-ols (Binolams) have emerged during the last five years ...
The use of 7-deoxycholic acid as a chiral template in the asymmetric syntheses of 1,1'-binaphthyl-2,...
Organocatalysis has emerged as a powerful synthetic tool in organic chemistry in the last few decade...
The efforts described in this dissertation initially focus on the asymmetric synthesis of axially ch...
The efforts described in this dissertation initially focus on the asymmetric synthesis of axially ch...
Herein we disclose a scalable organocatalytic direct arylation approach for the regio- and atroposel...
The lithiation, of the secondary chloride 2, catalyzed by binaphthyl derivatives, i.e. BINAM 4, BINO...
Pierwsza reakcja sprzęgania pierścieni arylowych katalizowanego miedzią została przeprowadzona przez...
Axially chiral biaryls, as exemplified by 1,1’-bi-2-naphthol (BINOL), are key components of catalyst...
Condensations of aromatic aldehydes with 2,2′-diamino-1,1′ -binaphthyl or 2-amino-2′-hydroxy-1,1′-bi...