Complementarity of LA-ICP-MS and petrography in the analysis of Neolithic pottery from the Scheldt River valley, Belgium

This paper presents the results of laser ablation - inductively coupled plasma - mass spectrometry (LA-ICP-MS) analysis of the clay fraction in 70 Late Mesolithic and Early/Middle Neolithic pottery sherds from the Scheldt basin and 10 sampled sediments. The elemental concentration results were visualized using multivariate chemometric techniques and compared to the results of petrographic analysis of the same ceramics in order to investigate the complementarity of both approaches. In addition, the results for the pottery and sediments were compared for clay sourcing purposes. Overall, the elemental analysis was able to confirm part of the observations from the petrographic analysis. However, a large part of the ceramics chemical clustering was driven by heterogeneity in the elemental composition that does not stem from differences in the clay source used. Furthermore, no conclusions could be drawn on the use of the sampled sediments for pottery production. Therefore, it is concluded that LA-ICP-MS analysis of the clay fraction in pottery can complement petrography, but petrographic analysis remains indispensable for clay sourcing of pottery from northern Belgium