Atomic Layer Deposition of Textured Li4Ti5O12 A High Power and Long Cycle Life Anode for Lithium Ion Thin Film Batteries

The zero strain Li4Ti5O12 is an attractive anode material for 3D solid state thin film batteries TFB to power upcoming autonomous sensor systems. Herein, Li4Ti5O12 thin films fabricated by atomic layer deposition ALD are electrochemically evaluated for the first time. The developed ALD process with a growth per cycle of 0.6 cycle amp; 8722;1 at 300 C enables high quality and dense spinel films with superior adhesion after annealing. The short lithium ion diffusion pathways of the nanostructured 30 nm films result in excellent electrochemical properties. Planar films reveal 98 of the theoretical capacity with 588 mAh cm amp; 8722;3 at 1 C. Substrate dependent film texture is identified as a key tuning parameter for exceptional C rate performance. The highly parallel grains of a strong out of plane 111 texture allow capacities of 278 mAh cm amp; 8722;3 at extreme rates of 200 C. Outstanding cycle performance is demonstrated, resulting in 97.9 capacity retention of the initial 366 mAh cm amp; 8722;3 after 1000 cycles at 100 C. Compared to other deposition techniques, the superior performance of ALD Li4Ti5O12 is a breakthrough towards scalable high power 3D TFB