Fac -to- mer isomerization triggers hydride transfer from Mn( i ) complex fac -[(dppm)Mn(CO) 3 H]

[(dmpe)2MnH(C2H4)] as a Source of a Low-Coordinate Ethyl Manganese(I) Species: Reactions with Primary Silanes, H2, and Isonitriles

Jeffrey S. Price (1425712)
David J. H. Emslie (1425715)
Ignacio Vargas-Baca (1589005)
James F. Britten (1483885)

September 2018

Wilkinson’s manganese(I) ethylene hydride complex trans-[(dmpe)2MnH(C2H4)] (1) reacts as a source ...

Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η 5 -C 5 H 5 )M(CO) 3 H (M = Mo, W) and Bases

Belkova, Natalia
Gutsul, Evgenii
Filippov, Oleg
Levina, Vladislava
Valyaev, Dmitry,
Epstein, Lina
Lledos, Agusti
Shubina, Elena

March 2006

International audienceThe interaction of CpM(CO)3H (M = Mo, W) hydrides as proton donors with differ...

Exploration of Ligand-Centered Hydride Transfer in La/Y-Catalyzed Deoxygenative Reduction of Tertiary Amides with Pinacolborane

Qian Gao (146991)
Yu-Hang Li (680116)
De-Zhan Chen (2556082)
Jian-Biao Liu (1711108)

January 2023

A number of rare-earth metals and actinides have proven to be active in a wide variety of atom-effic...

Fac -to- mer isomerization triggers hydride transfer from Mn( i ) complex fac -[(dppm)Mn(CO) 3 H]

Osipova, Elena
Gulyaeva, Ekaterina
Kireev, Nikolay
Kovalenko, Sergey
Bijani, Christian
Canac, Yves
Valyaev, Dmitry, A.
Filippov, Oleg
Belkova, Natalia
Shubina, Elena

April 2022

International audienceLow-temperature IR and NMR studies combined with DFT calculations revealed the...

The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes

Osipova, Elena, S
Kovalenko, Sergey, A
Gulyaeva, Ekaterina, S
Kireev, Nikolay, V
Pavlov, Alexander, A
Filippov, Oleg, A
Danshina, Anastasia, A
Valyaev, Dmitry, A
Canac, Yves
Shubina, Elena, S
Belkova, Natalia, V

January 2023

International audienceAcid-base characteristics (acidity, pKa, and hydricity, ΔG°H− or kH−) of metal...

Hydrogen bonding to carbonyl hydride complex Cp*Mo(PMe3)2(CO)H and its role in proton transfer

Dub, Pavel
Filippov, Oleg, A
Belkova, Natalia, V
Daran, Jean-Claude
Epstein, Lina, M
Poli, Rinaldo
Shubina, Elena, S

January 2010

International audienceThe interaction of the carbonyl hydride complex Cp*Mo(PMe3)2(CO)H with Brønste...

Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H 3 (M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal

Andrieu, J.
Belkova, N.
Besora, M.
Collange, E.
Epstein, L.
Lledós, A.
Poli, Rinaldo
Revin, P.
Shubina, E.
Vorontsov, E.

January 2003

International audienceThe protonation of complexes Cp*M(dppe)H3 (dppe is ethylenebis(diphenylphosphi...

Hydrogen Bonding and Proton Transfer to the Trihydride Complex [Cp*MoH3(dppe)]: IR, NMR, and Theoretical Investigations

Belkova, Natalia,
Revin, Pavel,
Besora, Maria
Baya, Miguel
Epstein, Lina,
Lledós, Agustí
Poli, Rinaldo
Shubina, Elena,
Vorontsov, Evgenii,

January 2006

International audienceThe interaction between [Cp*MoH3(dppe)] (dppe = Ph2PCH2CH2PPh2) and a variety ...

The Role of Solvent on the Mechanism of Proton Transfer to Hydride Complexes: The Case of the [W3PdS4H3(dmpe)3(CO)]+ Cubane Cluster

Algarra, Andrés G.
García Basallote, Manuel
Feliz Rodríguez, Marta
Fernández-Trujillo, M. Jesús
Llusar, Rosa
Safont Villarreal, Vicent Sixte

January 2010

The kinetics of reaction of the [W3PdS4H3(dmpe)3(CO)]+ hydride cluster (1+) with HCl has been measur...

Mechanism of formation of [(PMe3)(3)Rh(-C equivalent to C-R)(2)(H)] via C-H oxidative addition: Isomerization, alkyne exchange, and hydride replacement

The mechanism of formation of mer,trans-[(PMe3)(3)Rh(-Cequivalent toC-R)(2)H] from [(PMe3)(4)Rh(Me)]...

Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H Activation Mode

Buhaibeh, Ruqaya
Filippov, Oleg A
Bruneau-Voisine, Antoine
Willot, Jérémy
Duhayon, Carine
Valyaev, Dmitry A
Lugan, Noël
Canac, Yves
Sortais, Jean-Baptiste

January 2019

International audienceDeprotonation of the Mn NHC-phosphine complex fac-[MnBr(CO) (κ P,C-Ph PCH NHC)...

Kinetics and Mechanism of the Proton Transfer to Cp*Fe(dppe)H: Absence of a Direct Protonation at the Metal Site

Belkova, Natalia
Revin, Pavel
Epstein, Lina
Vorontsov, Evgenii
Bakhmutov, Vladimir
Shubina, Elena
Collange, Edmond
Poli, Rinaldo

January 2003

International audienceThe reaction between Cp*Fe(dppe)H and a number of different proton donors (2-f...

Chemistry of Group 13 Lewis acids

Branch, Catherine Steiner

January 2002

Reaction of 9-fluorenone with a Group 13 Lewis acid, MX3 (M = B, Al, Ga; X = Cl, Br), yields a Lewis...

Trapping of an Heterometallic Unsaturated Hydride: Structure and Properties of the Ammonia Complex [MoMnCp(μ-H)(μ-PPh2)(CO)5(NH3)]

M. Angeles Alvarez
Daniel García-Vivó
Estefanía Huergo
Miguel A. Ruiz

November 2018

Complexes displaying multiple bonds between different metal atoms have considerable synthetic potent...

[(dmpe)2MnH(C2H4)] as a Source of a Low-Coordinate Ethyl Manganese(I) Species: Reactions with Primary Silanes, H2, and Isonitriles

Jeffrey S. Price (1425712)
David J. H. Emslie (1425715)
Ignacio Vargas-Baca (1589005)
James F. Britten (1483885)

September 2018

Wilkinson’s manganese(I) ethylene hydride complex trans-[(dmpe)2MnH(C2H4)] (1) reacts as a source ...

Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η 5 -C 5 H 5 )M(CO) 3 H (M = Mo, W) and Bases

Belkova, Natalia
Gutsul, Evgenii
Filippov, Oleg
Levina, Vladislava
Valyaev, Dmitry,
Epstein, Lina
Lledos, Agusti
Shubina, Elena

March 2006

International audienceThe interaction of CpM(CO)3H (M = Mo, W) hydrides as proton donors with differ...

Exploration of Ligand-Centered Hydride Transfer in La/Y-Catalyzed Deoxygenative Reduction of Tertiary Amides with Pinacolborane

Qian Gao (146991)
Yu-Hang Li (680116)
De-Zhan Chen (2556082)
Jian-Biao Liu (1711108)

January 2023

A number of rare-earth metals and actinides have proven to be active in a wide variety of atom-effic...

Fac -to- mer isomerization triggers hydride transfer from Mn( i ) complex fac -[(dppm)Mn(CO) 3 H]

Osipova, Elena
Gulyaeva, Ekaterina
Kireev, Nikolay
Kovalenko, Sergey
Bijani, Christian
Canac, Yves
Valyaev, Dmitry, A.
Filippov, Oleg
Belkova, Natalia
Shubina, Elena

April 2022

International audienceLow-temperature IR and NMR studies combined with DFT calculations revealed the...

The Dichotomy of Mn–H Bond Cleavage and Kinetic Hydricity of Tricarbonyl Manganese Hydride Complexes

Osipova, Elena, S
Kovalenko, Sergey, A
Gulyaeva, Ekaterina, S
Kireev, Nikolay, V
Pavlov, Alexander, A
Filippov, Oleg, A
Danshina, Anastasia, A
Valyaev, Dmitry, A
Canac, Yves
Shubina, Elena, S
Belkova, Natalia, V

January 2023

International audienceAcid-base characteristics (acidity, pKa, and hydricity, ΔG°H− or kH−) of metal...

Hydrogen bonding to carbonyl hydride complex Cp*Mo(PMe3)2(CO)H and its role in proton transfer

Dub, Pavel
Filippov, Oleg, A
Belkova, Natalia, V
Daran, Jean-Claude
Epstein, Lina, M
Poli, Rinaldo
Shubina, Elena, S

January 2010

International audienceThe interaction of the carbonyl hydride complex Cp*Mo(PMe3)2(CO)H with Brønste...

Hydrogen bonding and proton transfer involving the trihydride complexes Cp*M(dppe)H 3 (M = Mo, W) and fluorinated alcohols: the competitive role of the hydride ligands and metal

Andrieu, J.
Belkova, N.
Besora, M.
Collange, E.
Epstein, L.
Lledós, A.
Poli, Rinaldo
Revin, P.
Shubina, E.
Vorontsov, E.

January 2003

International audienceThe protonation of complexes Cp*M(dppe)H3 (dppe is ethylenebis(diphenylphosphi...

Hydrogen Bonding and Proton Transfer to the Trihydride Complex [Cp*MoH3(dppe)]: IR, NMR, and Theoretical Investigations

Belkova, Natalia,
Revin, Pavel,
Besora, Maria
Baya, Miguel
Epstein, Lina,
Lledós, Agustí
Poli, Rinaldo
Shubina, Elena,
Vorontsov, Evgenii,

January 2006

International audienceThe interaction between [Cp*MoH3(dppe)] (dppe = Ph2PCH2CH2PPh2) and a variety ...

The Role of Solvent on the Mechanism of Proton Transfer to Hydride Complexes: The Case of the [W3PdS4H3(dmpe)3(CO)]+ Cubane Cluster

Algarra, Andrés G.
García Basallote, Manuel
Feliz Rodríguez, Marta
Fernández-Trujillo, M. Jesús
Llusar, Rosa
Safont Villarreal, Vicent Sixte

January 2010

The kinetics of reaction of the [W3PdS4H3(dmpe)3(CO)]+ hydride cluster (1+) with HCl has been measur...

Mechanism of formation of [(PMe3)(3)Rh(-C equivalent to C-R)(2)(H)] via C-H oxidative addition: Isomerization, alkyne exchange, and hydride replacement

The mechanism of formation of mer,trans-[(PMe3)(3)Rh(-Cequivalent toC-R)(2)H] from [(PMe3)(4)Rh(Me)]...

Phosphine-NHC Manganese Hydrogenation Catalyst Exhibiting a Non-Classical Metal-Ligand Cooperative H Activation Mode

Buhaibeh, Ruqaya
Filippov, Oleg A
Bruneau-Voisine, Antoine
Willot, Jérémy
Duhayon, Carine
Valyaev, Dmitry A
Lugan, Noël
Canac, Yves
Sortais, Jean-Baptiste

January 2019

International audienceDeprotonation of the Mn NHC-phosphine complex fac-[MnBr(CO) (κ P,C-Ph PCH NHC)...

Kinetics and Mechanism of the Proton Transfer to Cp*Fe(dppe)H: Absence of a Direct Protonation at the Metal Site

Belkova, Natalia
Revin, Pavel
Epstein, Lina
Vorontsov, Evgenii
Bakhmutov, Vladimir
Shubina, Elena
Collange, Edmond
Poli, Rinaldo

January 2003

International audienceThe reaction between Cp*Fe(dppe)H and a number of different proton donors (2-f...

Chemistry of Group 13 Lewis acids

Branch, Catherine Steiner

January 2002

Reaction of 9-fluorenone with a Group 13 Lewis acid, MX3 (M = B, Al, Ga; X = Cl, Br), yields a Lewis...

Trapping of an Heterometallic Unsaturated Hydride: Structure and Properties of the Ammonia Complex [MoMnCp(μ-H)(μ-PPh2)(CO)5(NH3)]

M. Angeles Alvarez
Daniel García-Vivó
Estefanía Huergo
Miguel A. Ruiz

November 2018

Complexes displaying multiple bonds between different metal atoms have considerable synthetic potent...

[(dmpe)2MnH(C2H4)] as a Source of a Low-Coordinate Ethyl Manganese(I) Species: Reactions with Primary Silanes, H2, and Isonitriles

Jeffrey S. Price (1425712)
David J. H. Emslie (1425715)
Ignacio Vargas-Baca (1589005)
James F. Britten (1483885)

September 2018

Wilkinson’s manganese(I) ethylene hydride complex trans-[(dmpe)2MnH(C2H4)] (1) reacts as a source ...

Intermolecular Hydrogen Bonding between Neutral Transition Metal Hydrides (η 5 -C 5 H 5 )M(CO) 3 H (M = Mo, W) and Bases

Belkova, Natalia
Gutsul, Evgenii
Filippov, Oleg
Levina, Vladislava
Valyaev, Dmitry,
Epstein, Lina
Lledos, Agusti
Shubina, Elena

March 2006

International audienceThe interaction of CpM(CO)3H (M = Mo, W) hydrides as proton donors with differ...

Exploration of Ligand-Centered Hydride Transfer in La/Y-Catalyzed Deoxygenative Reduction of Tertiary Amides with Pinacolborane

Qian Gao (146991)
Yu-Hang Li (680116)
De-Zhan Chen (2556082)
Jian-Biao Liu (1711108)

January 2023

A number of rare-earth metals and actinides have proven to be active in a wide variety of atom-effic...

Fac -to- mer isomerization triggers hydride transfer from Mn( i ) complex fac -[(dppm)Mn(CO) 3 H]

Abstract

Extracted data

Fac -to- mer isomerization triggers hydride transfer from Mn( i ) complex fac -[(dppm)Mn(CO) 3 H]

Abstract

Extracted data

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