Add to ORKGThe first chapter of this thesis describes the synthesis of compounds 82 and 83 , precursors for a radical polycyclization reaction.The results of this radical polycyclization model are also described in detail.The second chapter presents the initial route to diene-transmissive Diels-Alder precursors based upon an aldol condensation reaction as the key step for the introduction of chirality on the dienophile tether.The third chapter explains a second route to tetracyclic quassinoid intermediates via an S[subscript N]2' organocuprate displacement on an allylic acetate, 112 .The entire synthesis of the diene-transmissive Diels-Alder precursors 137 and 138 is described. Chapter four presents the results on the two diene-transmissive Diels-Alde...
The total synthesis of biologically active, naturally occurring substances is an ambitious task. Fas...
Herein is described the development of three synthetic transformations that are united in their bein...
The aromatic Claisen rearrangement and the Diels-Alder reaction have been widely used by synthetic c...
The first chapter of this thesis describes the synthesis of compounds 82 and 83 , precursors for a r...
The Diels-Alder reaction is one of the most powerful reactions available to the synthetic organic ch...
In the canon of reactions available to the organic chemist engaged in total synthesis, the Diels–Ald...
The central theme of this thesis can be considered the study and application of pericyclic reactions...
This thesis describes different strategies to desymmetrise 1,4-cyclohexadiene derivatives with conco...
In the canon of reactions available to the organic chemist engaged in total synthesis, the Diels–Ald...
The methodology for the synthesis of a new electron deficient 1,3-diene 44 was developed utilizing r...
The thesis describes the use of polycyclic quinodimethanes and related compounds as reactive inter...
This thesis describes the development of diastereotopic group selective processes allowing the desym...
The desire to synthesise molecules in new and improved ways is arguably what motivates research acro...
This thesis is focussed on the use of the diene-regenerative Diels-Alder reaction to assemble bicycl...
A tricyclic intermediate for the synthesis of quasimarin has been synthesized in 14 steps
The total synthesis of biologically active, naturally occurring substances is an ambitious task. Fas...
Herein is described the development of three synthetic transformations that are united in their bein...
The aromatic Claisen rearrangement and the Diels-Alder reaction have been widely used by synthetic c...
The first chapter of this thesis describes the synthesis of compounds 82 and 83 , precursors for a r...
The Diels-Alder reaction is one of the most powerful reactions available to the synthetic organic ch...
In the canon of reactions available to the organic chemist engaged in total synthesis, the Diels–Ald...
The central theme of this thesis can be considered the study and application of pericyclic reactions...
This thesis describes different strategies to desymmetrise 1,4-cyclohexadiene derivatives with conco...
In the canon of reactions available to the organic chemist engaged in total synthesis, the Diels–Ald...
The methodology for the synthesis of a new electron deficient 1,3-diene 44 was developed utilizing r...
The thesis describes the use of polycyclic quinodimethanes and related compounds as reactive inter...
This thesis describes the development of diastereotopic group selective processes allowing the desym...
The desire to synthesise molecules in new and improved ways is arguably what motivates research acro...
This thesis is focussed on the use of the diene-regenerative Diels-Alder reaction to assemble bicycl...
A tricyclic intermediate for the synthesis of quasimarin has been synthesized in 14 steps
The total synthesis of biologically active, naturally occurring substances is an ambitious task. Fas...
Herein is described the development of three synthetic transformations that are united in their bein...
The aromatic Claisen rearrangement and the Diels-Alder reaction have been widely used by synthetic c...