Octahydroxytetraazapentacenedione: New Organic Electrode Material for Fast and Stable Potassium Batteries

We report the synthesis and electrochemical characterization of octahydroxytetraazapentacenedione (OHTAPQ). The potassium batteries using OHTAPQ as electrode material delivered the specific capacity of 190 mAh g−1 at the current density of 0.6 A g−1. The use of the concentrated (2.2 M KPF6) diglyme-based electrolyte suppressed significantly the capacity fading of the potassium half-cells with OHTAPQ electrodes thus enabling their stable operation for 1200 charge-discharge cycles. Furthermore, OHTAPQ delivered the specific discharge capacity of 82–103 mAh g−1 at high current densities of 9–21 A g−1, which leads to high power densities approaching 41000 W kg−1. Thus, we demonstrate that the rationally designed organic electrode material enables high-capacity and high-power potassium batteries, which can be considered as a more environment-friendly and scalable alternative to the mainstream lithium-ion battery technology. © 2021 Elsevier B.V.This work was supported by the Russian Ministry of Science and Education (project 0089-2019-0010/AAAA-A19-119071190044-3 ). The XPS measurements were supported by the Ministry of Science and Higher Education of the Russian Federation (FEUZ-2020-0060), and Theme “Electron”, AAAA-A18-118020190098-5 at IPT UrFU and IMP UB RAS . The solid-state NMR spectroscopy experiments were performed at the Center of the Shared Facilities of IPCP RAS and Research Resource Center of the Scientific Center “Chernogolovka” of RAS. PAT acknowledges the support from EU’s Horizon 2020 ERA-Chair project ExCEED, grant agreement No 952008