The complex bonding and redox properties of actinide elements are much less understood compared to common main group and transition metal elements. This is likely the result of fewer chemical studies, due to the challenges of working with these radioactive elements. Nevertheless, understanding the chemical behavior of these elements, and how they differ from the lanthanide series, is crucial for nuclear materials processing and waste management. Along these lines, the first chapter discusses the interactions of an ONO-chelating redox-active ligand with uranium. Uranium derivatives of a dioxophenoxazine ligand, (DOPOq)2UO2, (DOPOsq)UI2(THF)2, (DOPOcat)UI(THF)2, and Cp*U(DOPOcat)(THF)2 (DOPO = 2,4,6,8-tetra-tert-butyl-1-oxo-1H-phenoxazin-9-ol...
With the ever-diminishing reserves of fossil fuels, it is inevitable that nuclear power will represe...
The effects of the ligand field are generally on the same order of magnitude as spin-orbit coupling ...
Chapter one introduces uranium oxo chemistry with a focus on the structure, oxogroup reactivity and...
The complex bonding and redox properties of actinide elements are much less understood compared to c...
Investigation of uranium(IV) complexes chelated by a tridentate amine, H3RITA (H3RITA = (MesNHCH2CH2...
The entire dissertation/thesis text is included in the research.pdf file; the official abstract appe...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
The aim of the work described in this thesis was to develop a more extensive knowledge of the chemi...
Synthesis, Characterization and Reactivity of Organometallic Complexes of Uranium and Plutonium in t...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
The mobility of the early actinide (An) elements uranium, neptunium, and plutonium is dependent on a...
The coordination chemistry of uranium is not well understood. This fact is at the crux of all issues...
The mobility of the early actinide (An) elements uranium, neptunium, and plutonium is dependent on a...
Known primarily for its single electron chemistry, controlling the electronics at uranium to facilit...
With the ever-diminishing reserves of fossil fuels, it is inevitable that nuclear power will represe...
The effects of the ligand field are generally on the same order of magnitude as spin-orbit coupling ...
Chapter one introduces uranium oxo chemistry with a focus on the structure, oxogroup reactivity and...
The complex bonding and redox properties of actinide elements are much less understood compared to c...
Investigation of uranium(IV) complexes chelated by a tridentate amine, H3RITA (H3RITA = (MesNHCH2CH2...
The entire dissertation/thesis text is included in the research.pdf file; the official abstract appe...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
The aim of the work described in this thesis was to develop a more extensive knowledge of the chemi...
Synthesis, Characterization and Reactivity of Organometallic Complexes of Uranium and Plutonium in t...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
While crucial advancements have been made in understanding transition metal−nitrogen interactions, t...
The mobility of the early actinide (An) elements uranium, neptunium, and plutonium is dependent on a...
The coordination chemistry of uranium is not well understood. This fact is at the crux of all issues...
The mobility of the early actinide (An) elements uranium, neptunium, and plutonium is dependent on a...
Known primarily for its single electron chemistry, controlling the electronics at uranium to facilit...
With the ever-diminishing reserves of fossil fuels, it is inevitable that nuclear power will represe...
The effects of the ligand field are generally on the same order of magnitude as spin-orbit coupling ...
Chapter one introduces uranium oxo chemistry with a focus on the structure, oxogroup reactivity and...