Two new monothiocarbamate ligands have been prepared and their coordination chemistry has been investigated. Potassium pyrrole-N-carbothioate, prepared from potassium pyrrolate and COS, is a white, air sensitive solid which reacts with NiBr2 and PdBr2 to yield 2:1 ligand to metal compounds. The Ni compound has been characterized by IR spectroscopic studies as well as a detailed magnetic study. Results show that the Ni(II) compound is a dimer with one paramagnetic and one diamagnetic Ni center. The magnetic moment is 2.53 ± 0.05 B.M. per Ni atom in the range 9.7–66.6 K. The Pd compound of the pyrrole-N-carbothioate ligand is apparently monomeric and four-coordinate. This is the first example of a simple bis-bidentate monothiocarbamate comple...
Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiornorpholine-4-carbodithioate complexes of ...
The Ni(II), Pd(II) and Pt(II) chelates of 2-amino- cyclopentene-l-dithiocarboxylic acid (ACDA) are d...
New monometallic complex salts of the form X-2[M(L)(2)] [M = Ni2+, X = (CH3)(2)NH2+(1); M = Ni2+, X ...
Two new monothiocarbamate ligands have been prepared and their coordination chemistry has been inves...
This bis(pyridine) adduct of the Ni(II) complex of pyrrole-N-carbothioate, Ni(ptc)2(py)2 has been sy...
This bis(pyridine) adduct of the Ni(II) complex of pyrrole-N-carbothioate, Ni(ptc)2(py)2 has been sy...
A new series of manganese(III), cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) comple...
A new series of manganese(III), cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) comple...
The syntheses of two new monothiocarbamate ligands and selected transition element complexes of each...
The syntheses of two new monothiocarbamate ligands and selected transition element complexes of each...
Triammonium-N-dithiocarboxyiminodiacetate, (NH4)(3)L, a new dithiocarbamato derivative of iminodiace...
The dithioester (CH2)4NCS2CH3 (PyDTM, 1-pyrrolidinecarbodithioate methyl ester) has been prepared by...
The dithioester (CH2)4NCS2CH3 (PyDTM, 1-pyrrolidinecarbodithioate methyl ester) has been prepared by...
Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiornorpholine-4-carbodithioate complexes of ...
The Ni(II), Pd(II) and Pt(II) chelates of 2-amino- cyclopentene-l-dithiocarboxylic acid (ACDA) are d...
Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiornorpholine-4-carbodithioate complexes of ...
The Ni(II), Pd(II) and Pt(II) chelates of 2-amino- cyclopentene-l-dithiocarboxylic acid (ACDA) are d...
New monometallic complex salts of the form X-2[M(L)(2)] [M = Ni2+, X = (CH3)(2)NH2+(1); M = Ni2+, X ...
Two new monothiocarbamate ligands have been prepared and their coordination chemistry has been inves...
This bis(pyridine) adduct of the Ni(II) complex of pyrrole-N-carbothioate, Ni(ptc)2(py)2 has been sy...
This bis(pyridine) adduct of the Ni(II) complex of pyrrole-N-carbothioate, Ni(ptc)2(py)2 has been sy...
A new series of manganese(III), cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) comple...
A new series of manganese(III), cobalt(II), nickel(II), zinc(II), cadmium(II) and mercury(II) comple...
The syntheses of two new monothiocarbamate ligands and selected transition element complexes of each...
The syntheses of two new monothiocarbamate ligands and selected transition element complexes of each...
Triammonium-N-dithiocarboxyiminodiacetate, (NH4)(3)L, a new dithiocarbamato derivative of iminodiace...
The dithioester (CH2)4NCS2CH3 (PyDTM, 1-pyrrolidinecarbodithioate methyl ester) has been prepared by...
The dithioester (CH2)4NCS2CH3 (PyDTM, 1-pyrrolidinecarbodithioate methyl ester) has been prepared by...
Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiornorpholine-4-carbodithioate complexes of ...
The Ni(II), Pd(II) and Pt(II) chelates of 2-amino- cyclopentene-l-dithiocarboxylic acid (ACDA) are d...
Piperidine-, morpholine-4-, N-methylpiperazine-4- and thiornorpholine-4-carbodithioate complexes of ...
The Ni(II), Pd(II) and Pt(II) chelates of 2-amino- cyclopentene-l-dithiocarboxylic acid (ACDA) are d...
New monometallic complex salts of the form X-2[M(L)(2)] [M = Ni2+, X = (CH3)(2)NH2+(1); M = Ni2+, X ...