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Insertion of Benzylisocyanide into a Zr-P bond and Rearrangement. Atom-Economical Synthesis of a Phosphaalkene

  • MacMillian, Samantha N
  • Tanski, Joseph M
  • Waterman, Rory
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Publication date
July 2007
Icon DOI
10.1039/b709506f
Publisher
UVM ScholarWorks
ISSN
1359-7345
Citation count (estimate)
19

Abstract

Reaction of (N3N)ZrPHPh (1, N3N = N(CH2CH2NSiMe3)33−) with PhCH2NC affords the 1,1-insertion product (N3N)Zr[C(PHPh)NCH2Ph] (2), which thermally rearranges to the phosphaalkene-containing complex, (N3N)Zr[N(CH2Ph)C(H)PPh] (3)

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