Reactivity of HTcO4 with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations

Speciation of Technetium in Carbonate Media under Helium Ions and γ Radiation

Ghalei, Mohammad
Vandenborre, Johan
Poineau, Frederic
Blain, Guillaume
Solari, Pier-Lorenzo
Rôques, Jerome
Haddad, Ferid
Fattahi, Massoud

October 2018

Technetium carbonates complexes produced by chemical, electrochemical and radiolytic methods have be...

Stabilization of metastable hydrogen trioxide (HOOOH) and the hydrotrioxyl radical (HOOOradical dot) by complexation with sulfuric acid. A theoretical study

Cannon, Daniel
Tuttle, Tell
Koller, J.
Plesnicar, B.

April 2013

The formation of bimolecular complexes of HOOOH and the HOOOﰀ radical with sulfuric acid (H2SO4– HOO...

Complexing of Sulfur(IV) Oxide with Hexamethylenetetramine and Hexamethylenediamine in Aqueous Solutions

Khoma, R. E.
Shestaka, A. A.
Gavrilenko, M. I.
Sokhranenko, G. P.
Gel’mbol’dt, V. O.

January 2011

Interaction in the sulfur(IV) oxide–hexamethylenetetramine (hexamethylenediamine)–water systems was ...

Reactivity of HTcO4 with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations

Poineau, F.
Weck, P.F.
Burton-Pye, B.P.
Denden, I.
Kim, E.
Kerlin, W.
German, K.E.
Fattahi, M.
Francesconi, L.C.
Sattelberger, A.P.
Czerwinski, K.R.

January 2013

The reaction between HTcO4 and MeOH in 13 M H2SO4 was investigated by 99Tc NMR, UV-visible and X-ray...

Speciation of Technetium in Sulfuric Acid/Hydrogen Sulfide Solutions

Ferrier, M.
Roques, J.
Poineau, F.
P. Sattelberger, A.
Unger, J.
R. Czerwinski, K.

January 2014

The reaction between TcVII and H2S(g) in 12 M H2SO4 has been studied. This reaction produced a black...

Speciation of Heptavalent Technetium in Sulfuric Acid: Structural and Spectroscopic Studies.

Poineau, Frederic
Weck, Philippe F.
German, Konstantin
Maruk, Alesya
Kirakosyan, Gayane
Lukens, Wayne
Rego, Daniel B.
Sattelberger, Alfred P.
Czerwinski, Kenneth R.

June 2010

The speciation of Tc(VII) in 12 M sulfuric acid was studied by NMR, UV-visible and XAFS spectroscopy...

On the nature of heptavalent technetium in concentrated nitric and perchloric acid

Poineau, F.
Burton-Pye, B.P.
Maruk, A.
Kirakosyan, G.
Denden, I.
Rego, D.B.
Johnstone, E.V.
Sattelberger, A.P.
Fattahi, M.
Francesconi, L.C.
German, K.E.
Czerwinski, K.R.

January 2013

The speciation of Tc(+7) was performed in HClO4 and HNO3 by 99-Tc NMR, UV-Vis and XAFS spectroscopy....

Behavior of Heptavalent Technetium in Sulfuric Acid under α‑Irradiation: Structural Determination of Technetium Sulfate Complexes by X‑ray Absorption Spectroscopy and First Principles Calculations

I. Denden (1837933)
F. Poineau (1837918)
M. L. Schlegel (1837939)
J. Roques (1837942)
P. Lorenzo Solari (1837930)
G. Blain (1837936)
K. R. Czerwinski (1837915)
R. Essehli (1837924)
J. Barbet (1837927)
M. Fattahi (1837921)

March 2014

The effect of α-radiolysis on the behavior of heptavalent technetium has been investigated in 13 and...

XAS study of technetium(IV) polymer formation in mixed sulphate/chloride media

Vichot, L.
Ouvrard, G.
Montavon, Gilles,
Fattahi, M.
Musikas, C.
Grambow, Bernd

January 2002

X-ray absorption spectroscopy has been used to establish polymer formation of Tc(IV) in aqueous solu...

Ammonium Pertechnetate in Mixtures of Trifluoromethanesulfonic Acid and Trifluoromethanesulfonic Anhydride

Zegke, Markus
Grödler, Dennis
Klein, Axel
Breugst, Martin
Abram, Ulrich
Strub, Erik
Wickleder, Mathias S.
Roca Jungfer, Maximilian
Haseloer, Alexander
Kreuter, Meike
Neudörfl, Jörg M.
Sittel, Thomas
James, Christopher M.
Rothe, Jörg
Altmaier, Marcus

January 2022

Ammonium pertechnetate reacts in mixtures of trifluoromethanesulfonic anhydride and trifluoromethane...

EXAFS and DFT: Evidence for the [TcO]2+ core

Breynaert, Eric
Kirschhock, Christine
Maes, André

April 2009

Technetium, an unusual element whereof only radioactive isotopes exist, is characterised by a very r...

Theoretical study on the reactivity of sulfate species with hydrocarbons

Ma, Qisheng
Ellis, Gregory S.
Amrani, Alon
Zhang, Tongwei

September 2008

The abiotic, thermochemically controlled reduction of sulfate to hydrogen sulfide coupled with the o...

Speciation of Technetium in Carbonate Media under Helium Ions and Y Radiation

Ghalei, Mohammad
Vandenborre, Johan
Poineau, Frederic
Blain, Guillaume
Solari, Pier Lorenzo
Rôques, Jérôme
Haddad, Ferid
Fattahi, Massoud
Lu, Fei
Sun, Hong
Zhang, Hui

October 2018

Technetium carbonates complexes produced by chemical, electrochemical and radiolytic methods have be...

Features of Interaction in the Sulfur(IV) Oxide–Hexamethylenetetramine–Water System: A First Example of Identification of the Product with a Sulfur–Carbon Bond

Khoma, R. E.
Shestaka, A. A.
Shishkin, O. V.
Baumer, V. N.
Brusilovskii, Yu. E.
Koroeva, L. V.
Ennan, A. A.
Gel’mbol’d, V. O.

January 2011

Hexamethylenetetramine (HMTA) is a ligand in the synthesis of coordination compounds and also is use...

Speciation of Technetium in Carbonate Media under Helium Ions and γ Radiation

Ghalei, Mohammad
Vandenborre, Johan
Poineau, Frederic
Blain, Guillaume
Solari, Pier-Lorenzo
Rôques, Jerome
Haddad, Ferid
Fattahi, Massoud

October 2018

Technetium carbonates complexes produced by chemical, electrochemical and radiolytic methods have be...

Stabilization of metastable hydrogen trioxide (HOOOH) and the hydrotrioxyl radical (HOOOradical dot) by complexation with sulfuric acid. A theoretical study

Cannon, Daniel
Tuttle, Tell
Koller, J.
Plesnicar, B.

April 2013

The formation of bimolecular complexes of HOOOH and the HOOOﰀ radical with sulfuric acid (H2SO4– HOO...

Complexing of Sulfur(IV) Oxide with Hexamethylenetetramine and Hexamethylenediamine in Aqueous Solutions

Khoma, R. E.
Shestaka, A. A.
Gavrilenko, M. I.
Sokhranenko, G. P.
Gel’mbol’dt, V. O.

January 2011

Interaction in the sulfur(IV) oxide–hexamethylenetetramine (hexamethylenediamine)–water systems was ...

Reactivity of HTcO4 with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations

Poineau, F.
Weck, P.F.
Burton-Pye, B.P.
Denden, I.
Kim, E.
Kerlin, W.
German, K.E.
Fattahi, M.
Francesconi, L.C.
Sattelberger, A.P.
Czerwinski, K.R.

January 2013

The reaction between HTcO4 and MeOH in 13 M H2SO4 was investigated by 99Tc NMR, UV-visible and X-ray...

Speciation of Technetium in Sulfuric Acid/Hydrogen Sulfide Solutions

Ferrier, M.
Roques, J.
Poineau, F.
P. Sattelberger, A.
Unger, J.
R. Czerwinski, K.

January 2014

The reaction between TcVII and H2S(g) in 12 M H2SO4 has been studied. This reaction produced a black...

Speciation of Heptavalent Technetium in Sulfuric Acid: Structural and Spectroscopic Studies.

Poineau, Frederic
Weck, Philippe F.
German, Konstantin
Maruk, Alesya
Kirakosyan, Gayane
Lukens, Wayne
Rego, Daniel B.
Sattelberger, Alfred P.
Czerwinski, Kenneth R.

June 2010

The speciation of Tc(VII) in 12 M sulfuric acid was studied by NMR, UV-visible and XAFS spectroscopy...

On the nature of heptavalent technetium in concentrated nitric and perchloric acid

Poineau, F.
Burton-Pye, B.P.
Maruk, A.
Kirakosyan, G.
Denden, I.
Rego, D.B.
Johnstone, E.V.
Sattelberger, A.P.
Fattahi, M.
Francesconi, L.C.
German, K.E.
Czerwinski, K.R.

January 2013

The speciation of Tc(+7) was performed in HClO4 and HNO3 by 99-Tc NMR, UV-Vis and XAFS spectroscopy....

Behavior of Heptavalent Technetium in Sulfuric Acid under α‑Irradiation: Structural Determination of Technetium Sulfate Complexes by X‑ray Absorption Spectroscopy and First Principles Calculations

I. Denden (1837933)
F. Poineau (1837918)
M. L. Schlegel (1837939)
J. Roques (1837942)
P. Lorenzo Solari (1837930)
G. Blain (1837936)
K. R. Czerwinski (1837915)
R. Essehli (1837924)
J. Barbet (1837927)
M. Fattahi (1837921)

March 2014

The effect of α-radiolysis on the behavior of heptavalent technetium has been investigated in 13 and...

XAS study of technetium(IV) polymer formation in mixed sulphate/chloride media

Vichot, L.
Ouvrard, G.
Montavon, Gilles,
Fattahi, M.
Musikas, C.
Grambow, Bernd

January 2002

X-ray absorption spectroscopy has been used to establish polymer formation of Tc(IV) in aqueous solu...

Ammonium Pertechnetate in Mixtures of Trifluoromethanesulfonic Acid and Trifluoromethanesulfonic Anhydride

Zegke, Markus
Grödler, Dennis
Klein, Axel
Breugst, Martin
Abram, Ulrich
Strub, Erik
Wickleder, Mathias S.
Roca Jungfer, Maximilian
Haseloer, Alexander
Kreuter, Meike
Neudörfl, Jörg M.
Sittel, Thomas
James, Christopher M.
Rothe, Jörg
Altmaier, Marcus

January 2022

Ammonium pertechnetate reacts in mixtures of trifluoromethanesulfonic anhydride and trifluoromethane...

EXAFS and DFT: Evidence for the [TcO]2+ core

Breynaert, Eric
Kirschhock, Christine
Maes, André

April 2009

Technetium, an unusual element whereof only radioactive isotopes exist, is characterised by a very r...

Theoretical study on the reactivity of sulfate species with hydrocarbons

Ma, Qisheng
Ellis, Gregory S.
Amrani, Alon
Zhang, Tongwei

September 2008

The abiotic, thermochemically controlled reduction of sulfate to hydrogen sulfide coupled with the o...

Speciation of Technetium in Carbonate Media under Helium Ions and Y Radiation

Ghalei, Mohammad
Vandenborre, Johan
Poineau, Frederic
Blain, Guillaume
Solari, Pier Lorenzo
Rôques, Jérôme
Haddad, Ferid
Fattahi, Massoud
Lu, Fei
Sun, Hong
Zhang, Hui

October 2018

Technetium carbonates complexes produced by chemical, electrochemical and radiolytic methods have be...

Features of Interaction in the Sulfur(IV) Oxide–Hexamethylenetetramine–Water System: A First Example of Identification of the Product with a Sulfur–Carbon Bond

Khoma, R. E.
Shestaka, A. A.
Shishkin, O. V.
Baumer, V. N.
Brusilovskii, Yu. E.
Koroeva, L. V.
Ennan, A. A.
Gel’mbol’d, V. O.

January 2011

Hexamethylenetetramine (HMTA) is a ligand in the synthesis of coordination compounds and also is use...

Speciation of Technetium in Carbonate Media under Helium Ions and γ Radiation

Ghalei, Mohammad
Vandenborre, Johan
Poineau, Frederic
Blain, Guillaume
Solari, Pier-Lorenzo
Rôques, Jerome
Haddad, Ferid
Fattahi, Massoud

October 2018

Technetium carbonates complexes produced by chemical, electrochemical and radiolytic methods have be...

Stabilization of metastable hydrogen trioxide (HOOOH) and the hydrotrioxyl radical (HOOOradical dot) by complexation with sulfuric acid. A theoretical study

Cannon, Daniel
Tuttle, Tell
Koller, J.
Plesnicar, B.

April 2013

The formation of bimolecular complexes of HOOOH and the HOOOﰀ radical with sulfuric acid (H2SO4– HOO...

Complexing of Sulfur(IV) Oxide with Hexamethylenetetramine and Hexamethylenediamine in Aqueous Solutions

Khoma, R. E.
Shestaka, A. A.
Gavrilenko, M. I.
Sokhranenko, G. P.
Gel’mbol’dt, V. O.

January 2011

Interaction in the sulfur(IV) oxide–hexamethylenetetramine (hexamethylenediamine)–water systems was ...

Reactivity of HTcO4 with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations

Abstract

Extracted data

Reactivity of HTcO4 with methanol in sulfuric acid: Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations

Abstract

Extracted data

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