POVIŠENE RAZINE OPASNIH ELEMENATA U TRAGOVIMA (CD, CU, PB, SE, ZN) U TKIVIMA PTICA U KONTEKSTU RAŠKIM UGLJENOM ONEČIŠĆENA OKOLIŠA

The mining and burning of Croatian Raša coal had resulted in release of various contaminants into the local environment. They have remained in the local soil, water, and plants, and became available to animals through their consumption. In this study, tissue samples from a total of 12 birds from the Raša area and 8 birds from a control area were subjected to multi-element analysis (Al, V, Cr, Mn, Fe, Co, Cu, Zn, As, Se, Mo, Cd, Pb) by ICP-MS. The obtained results showed increased Se and Cd concentrations in some bird tissue samples compared to the control area. The highest concentrations of Cu, Zn, and Se were found in the liver, while the highest concentrations of Cd and Pb were found in the kidneys. Although some hazardous trace elements were elevated in the tissues of game species, the risk of consuming meat and offal of such species has been found to be very low.Rudarske i industrijske aktivnosti povezane s raškim ugljenom rezultirale su ispuštanjem raznih onečišćujućih tvari u lokalni okoliš. Te tvari i dalje su prisutne u lokalnome tlu, vodi i biljkama te su dostupne životinjama unosom hrane. U ovome istraživanju uzorci tkiva ukupno 12 ptica iz područja Raše te 8 ptica iz kontrolnoga područja podvrgnuti su multielementnoj (Al, V, Cr, Mn, Fe, Co, Cu, Zn, As, Se, Mo, Cd, Pb) analizi s pomoću metode ICP-MS. Dobiveni rezultati pokazali su povišene koncentracije Se i Cd u nekim uzorcima tkiva ptica u usporedbi s kontrolnim područjem. Najveće koncentracije Cu, Zn i Se nađene su u uzorcima jetre, dok su najviše koncentracije Cd i Pb nađene u bubrezima. Iako su neki opasni elementi u tragovima povišeni u tkivima prikupljenih divljih ptica, analizom podataka utvrđeno je da je rizik od prehrambena unosa (meso i iznutrice) tih vrsta vrlo nizak