Thermodynamic characterization of (E)-4-((4-methoxybenzylidene) amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione derivative on carbon steel corrosion in acidic medium

The detailed study of corrosion behaviour of carbon steel in 1M hydrochloric acid solution in the presence and absence of (E)-4-((4-methoxybenzylidene) amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione (3-Tz) was investigated using weight loss method at various temperatures from 303 to 333 K. The inhibitor showed 92.15% inhibition efficiency at its optimum concentration 5 x 10-2M at 303K and decreased at higher temperatures. The various parameters of activation determining the kinetic data such as energy, enthalpy and entropy at different concentrations of the inhibitor were evaluated and discussed. The thermodynamic parameters such as, equilibrium constant, adsorption heat and adsorption entropy were obtained. The adsorptive behaviour of(3-Tz) followed Langmuir-type isotherm. The standard free energies of adsorption were negative at different temperatures tested, suggesting better inhibition performance