Nonresonant Raman Spectrum Of Boron Doped Single Walled Carbon Nanotubes

In the present work, We use a force constant model to study the vibrationnel modes of boron doped single walled carbon nanotubes. This model is used to calculate the nonresonant Raman spectra of these nanomaterials in the framework of bond-polarisation theory by using either direct diagonalisation of the dynamical matrix or the spectral moments method. The effect of substitution of carbon by boron atoms shows that the higher Raman frequency region is dominated by a broad bond whereas the lower one is characterized by a shift of radial bonds.In the present work, We use a force constant model to study the vibrationnel modes of boron doped single walled carbon nanotubes. This model is used to calculate the nonresonant Raman spectra of these nanomaterials in the framework of bond-polarisation theory by using either direct diagonalisation of the dynamical matrix or the spectral moments method. The effect of substitution of carbon by boron atoms shows that the higher Raman frequency region is dominated by a broad bond whereas the lower one is characterized by a shift of radial bonds