The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp ring in a tosylimido-bridged cobaltadithiolene complex was investigated, and a probable intermediate was isolated and characterized. The presence of a large excess of PPh3 causes the formation of the imido- and phosphine-substituted Cp complex
A comparative study on the stereoselective synthesis of O,P,C-cage complexes is described using oxap...
© 2016 Taylor & Francis Group, LLC.The reactivity of organonickel sigma-complex [NiBr(Mes)(bpy)], wh...
The first homoleptic cobalt phosphanido complex [K(thf)(4)][Co{1,2-(PtBu2)(2)C2B10H12}(2)] (1) was p...
The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp r...
We have found that {eta}{sup 5}-methylcyclopentadienyl- (triphenylphosphine)dimethylcobalt(III) (1) ...
The aim of this study was to investigate the mechanism of phosphine induced migratory carbonyl inser...
The synthesis of the first terminal imido complex of cobalt, [PhBP3]CoN-p-tolyl, is reported. Its sy...
Not as innocent as it looks: Reaction of the phosphinidene complex 1 with tBuCP leads, via a WP trip...
The reaction of triethylamine with the [4 + 2] cycloadducts of phosphole sulfides and 3-bromo-<i>N</...
The substitution of trimethylphosphine for triphenylphosphine in {eta}{sup 5}-cyclopentadienyl-bis-t...
Reaction of the CoI complex [(TIMMNmes)CoI](PF6) (1) (TIMMNmes=tris-[2-(3-mesityl-imidazolin-2-ylide...
A cationic Rh(III) aryl-methyl complex, bearing a thiophosphoryl-based SCS-type pincer ligand, unde...
In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structu...
The reaction between diphosphorus derivatives [(ClImDipp)P2(Dipp)]OTf (1[OTf]) and [(ClImDipp)P2(Dip...
A method for the generation of transition metal–phosphorus multiple bonds has been developed using t...
A comparative study on the stereoselective synthesis of O,P,C-cage complexes is described using oxap...
© 2016 Taylor & Francis Group, LLC.The reactivity of organonickel sigma-complex [NiBr(Mes)(bpy)], wh...
The first homoleptic cobalt phosphanido complex [K(thf)(4)][Co{1,2-(PtBu2)(2)C2B10H12}(2)] (1) was p...
The mechanism of phosphine- and phosphite-induced migration of the imido group from sulfur to a Cp r...
We have found that {eta}{sup 5}-methylcyclopentadienyl- (triphenylphosphine)dimethylcobalt(III) (1) ...
The aim of this study was to investigate the mechanism of phosphine induced migratory carbonyl inser...
The synthesis of the first terminal imido complex of cobalt, [PhBP3]CoN-p-tolyl, is reported. Its sy...
Not as innocent as it looks: Reaction of the phosphinidene complex 1 with tBuCP leads, via a WP trip...
The reaction of triethylamine with the [4 + 2] cycloadducts of phosphole sulfides and 3-bromo-<i>N</...
The substitution of trimethylphosphine for triphenylphosphine in {eta}{sup 5}-cyclopentadienyl-bis-t...
Reaction of the CoI complex [(TIMMNmes)CoI](PF6) (1) (TIMMNmes=tris-[2-(3-mesityl-imidazolin-2-ylide...
A cationic Rh(III) aryl-methyl complex, bearing a thiophosphoryl-based SCS-type pincer ligand, unde...
In situ-generated metal carbonyl-complexed cyclopropenylphosphinidenes undergo a sequence of structu...
The reaction between diphosphorus derivatives [(ClImDipp)P2(Dipp)]OTf (1[OTf]) and [(ClImDipp)P2(Dip...
A method for the generation of transition metal–phosphorus multiple bonds has been developed using t...
A comparative study on the stereoselective synthesis of O,P,C-cage complexes is described using oxap...
© 2016 Taylor & Francis Group, LLC.The reactivity of organonickel sigma-complex [NiBr(Mes)(bpy)], wh...
The first homoleptic cobalt phosphanido complex [K(thf)(4)][Co{1,2-(PtBu2)(2)C2B10H12}(2)] (1) was p...