A new zero-dimensional alkali-metal tin mixed halide, K6Sn4F12I2•0.5H2O, is synthesized by a hydrothermal method. It crystallizes in the cubic centrosymmetric space group of Fd-3m (No. 227) and its structure consists of crystal water molecules and ordered arranged [Sn4F12I4] fundamental structural blocks trapped in [K18] cages. Interestingly, K6Sn4F12I2•0.5H2O exhibits a color change from colorless to orange when exposed to air. Experimental measurements combined with theoretical calculations reveal that the color change in K6Sn4F12I2•0.5H2O is attributed to the loss of crystal water
Phase separation resulting in a single-crystal-single-crystal transition accompanied by a polycrysta...
The hydrothermal syntheses and crystal structures of three new scandium fluorides are reported. [enH...
Direct treatment (1:1) of MCl3 (M = Sc, Y or La) with SnCl4 in thf provides colourless compounds of ...
A new zero-dimensional alkali-metal tin mixed halide, K6Sn4F12I2•0.5H2O, is synthesized by a hydroth...
A new perovskite stoichiometric alkali tin dihalides compound, Cs<sub>3</sub>Sn<sub>3</sub>F<sub>2<...
The title compound, [SnCl4(H2O)2]·6H2O, was crystallized according to the solid–liquid phase diagram...
Three tin compounds, Cs8Sn44, Cs8Ga8Sn38, and Cs8Zn4Sn42, representative of the type-I clathrate hyd...
Three tin compounds, Cs8Sn44, Cs8Ga8Sn38, and Cs8Zn4Sn42, representative of the type-I clathrate hyd...
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Görgeyite, K2Ca5(SO4)6··H2O, is a very rare monoclinic double salt found in evaporites related to th...
The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlora...
Both title compounds show an antifluorite-like arrangement of (CH3)4N+ cations and TeCl6 2- anions. ...
Reaction of tin(II) chloride with Li(CPhCPh2) at –78 °C in diethyl ether–hexane–tetrahydrofuran affo...
The crystal structure of the title compound, [Sn(C6H5)3Cl(H2O)]·C12H8N2, which was refined in t...
NOTE: Text or symbols not renderable in plain ASCII are indicated by [...]. Abstract is included in...
Phase separation resulting in a single-crystal-single-crystal transition accompanied by a polycrysta...
The hydrothermal syntheses and crystal structures of three new scandium fluorides are reported. [enH...
Direct treatment (1:1) of MCl3 (M = Sc, Y or La) with SnCl4 in thf provides colourless compounds of ...
A new zero-dimensional alkali-metal tin mixed halide, K6Sn4F12I2•0.5H2O, is synthesized by a hydroth...
A new perovskite stoichiometric alkali tin dihalides compound, Cs<sub>3</sub>Sn<sub>3</sub>F<sub>2<...
The title compound, [SnCl4(H2O)2]·6H2O, was crystallized according to the solid–liquid phase diagram...
Three tin compounds, Cs8Sn44, Cs8Ga8Sn38, and Cs8Zn4Sn42, representative of the type-I clathrate hyd...
Three tin compounds, Cs8Sn44, Cs8Ga8Sn38, and Cs8Zn4Sn42, representative of the type-I clathrate hyd...
Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала
Görgeyite, K2Ca5(SO4)6··H2O, is a very rare monoclinic double salt found in evaporites related to th...
The title compound, [Sn(H2O)3](ClO4)2, was synthesized by the redox reaction of copper(II) perchlora...
Both title compounds show an antifluorite-like arrangement of (CH3)4N+ cations and TeCl6 2- anions. ...
Reaction of tin(II) chloride with Li(CPhCPh2) at –78 °C in diethyl ether–hexane–tetrahydrofuran affo...
The crystal structure of the title compound, [Sn(C6H5)3Cl(H2O)]·C12H8N2, which was refined in t...
NOTE: Text or symbols not renderable in plain ASCII are indicated by [...]. Abstract is included in...
Phase separation resulting in a single-crystal-single-crystal transition accompanied by a polycrysta...
The hydrothermal syntheses and crystal structures of three new scandium fluorides are reported. [enH...
Direct treatment (1:1) of MCl3 (M = Sc, Y or La) with SnCl4 in thf provides colourless compounds of ...