Monte Carlo Radiative Transfer Simulation to Analyze the Spectral Index for Remote Detection of Oil Dispersed in the Southern Baltic Sea Seawater Column: The Role of Water Surface State

The article presents the results of simulations that take into account the optical parameters of the selected sea region (from literature data on the southern Baltic Sea) and two optically extreme types of crude oil (from historical data) which exist in the form of a highly watered-down oil-in-water emulsion (10 ppm). The spectral index was analyzed based on the results of modeling the radiance reflectance distribution for almost an entire hemisphere of the sky (zenith angle from 0 to 80°). The spectral index was selected and is universal for all optically different types of oil (wavelengths of 650 and 412 nm). The possibility of detecting pollution in the conditions of the wavy sea surface (as a result of wind of up to 10 m/s) was studied. It was also shown that if the viewing direction is close to a direction perpendicular to the sea surface, observations aimed at determining the spectral index are less effective than observations under the zenith angle of incidence of sunlight for all azimuths excluding the direction of sunlight’s specular reflection