This paper reports on the comparison of three zirconium-based metal organic frameworks (MOFs) for the capture of carbon dioxide and ethanol vapour at ambient conditions. In terms of efficiency, two parameters were evaluated by experimental and modeling means, namely the nature of the ligands and the size of the cavities. We demonstrated that amongst three Zr-based MOFs, MIP-202 has the highest affinity for CO2 (−50 kJ·mol−1 at low coverage against around −20 kJ·mol−1 for MOF-801 and Muc Zr MOF), which could be related to the presence of amino functions borne by its aspartic acid ligands as well as the presence of extra-framework anions. On the other side, regardless of the ligand size, these three materials were able to adsorb similar amoun...
Developing Al-based metal–organic frameworks (MOFs) with moisture-resistance ability is a challenge ...
Zirconium-metal organic frameworks (Zr-MOFs) were synthesized with or without ammonium hydroxide as ...
Adsorption of carbon dioxide (CO2), as well as many other kinds of small molecules, is of importance...
International audienceThis paper reports on the comparison of three zirconium-based metal organic fr...
International audienceThis paper reports on the comparison of three zirconium-based metal organic fr...
International audienceThis paper reports on the comparison of three zirconium-based metal organic fr...
This scholarly research investigates synthesis of different Zr-MOFs and some of Al- MOFs and studies...
Metal-organic frameworks (MOFs) are a class of porous materials that are formed when inorganic metal...
International audienceThe discovery of naturally occurring linker‐based zirconium MOFs with permanen...
International audienceThe discovery of naturally occurring linker‐based zirconium MOFs with permanen...
International audienceThe discovery of naturally occurring linker‐based zirconium MOFs with permanen...
This thesis reports an investigation into metal-organic frameworks (MOFs) as candidate solid-state c...
PhDWith the emission of carbon dioxide (CO2) becoming an international worry due its role in climat...
This work aims to synthesize and characterize the Metal-organic frameworks (MOFs): MIP-202, MOF-801,...
CO2 uptake in zirconium MOF UiO-66 almost doubles with post-synthetic exchange of Zr by Ti. This was...
Developing Al-based metal–organic frameworks (MOFs) with moisture-resistance ability is a challenge ...
Zirconium-metal organic frameworks (Zr-MOFs) were synthesized with or without ammonium hydroxide as ...
Adsorption of carbon dioxide (CO2), as well as many other kinds of small molecules, is of importance...
International audienceThis paper reports on the comparison of three zirconium-based metal organic fr...
International audienceThis paper reports on the comparison of three zirconium-based metal organic fr...
International audienceThis paper reports on the comparison of three zirconium-based metal organic fr...
This scholarly research investigates synthesis of different Zr-MOFs and some of Al- MOFs and studies...
Metal-organic frameworks (MOFs) are a class of porous materials that are formed when inorganic metal...
International audienceThe discovery of naturally occurring linker‐based zirconium MOFs with permanen...
International audienceThe discovery of naturally occurring linker‐based zirconium MOFs with permanen...
International audienceThe discovery of naturally occurring linker‐based zirconium MOFs with permanen...
This thesis reports an investigation into metal-organic frameworks (MOFs) as candidate solid-state c...
PhDWith the emission of carbon dioxide (CO2) becoming an international worry due its role in climat...
This work aims to synthesize and characterize the Metal-organic frameworks (MOFs): MIP-202, MOF-801,...
CO2 uptake in zirconium MOF UiO-66 almost doubles with post-synthetic exchange of Zr by Ti. This was...
Developing Al-based metal–organic frameworks (MOFs) with moisture-resistance ability is a challenge ...
Zirconium-metal organic frameworks (Zr-MOFs) were synthesized with or without ammonium hydroxide as ...
Adsorption of carbon dioxide (CO2), as well as many other kinds of small molecules, is of importance...