Interpretation of Mineralization in the Western Carpathians (Polish Segment)—A Tectonic Mélange Approach

Quartz, carbonates and other minerals as e.g., realgar are present in veins and caverns in sedimentary rocks in the Western Carpathians. In the Polish segment, they have been characterized from the mineralogical, petrologic, and geochemical points of view, as well as fluid inclusions. Their characters are discussed from perspective of a description of particular types of chaotic complexes—the tectonic mélange zones, distinguished in the Western Carpathian area over the last two decades. The mélange zones are considered to be geochemical systems open to fluid flow, a site for mineral crystallization and/or migration zones of hydrocarbons and mineralized waters. In this context the tectonic mélange in the Jabłonki/Rabe vicinity (SE Poland, the Bieszczady region) in comparison to that of the Mszana Dolna tectonic window area are proposed as the examples. The trapping conditions of fluids (brine and methane) in the minerals in the mélange zones appear to have been 180–205 °C and ~550–570 bars, and 220 °C and 500 bars for calcite and quartz, respectively. The general trend of the increase in temperatures and pressures from west towards east and south-east in the mélange zones points to an increase in the degree of exhumation of different parts of the Carpathians