Impacts of biogenic isoprene emission on ozone air quality in the Seoul metropolitan area

The impacts of biogenic isoprene emission on ozone (O-3) air quality during an episode under weak synoptic forcing in the Seoul metropolitan area (SMA), Republic of Korea, are investigated using the Community Multiscale Air Quality (CMAQ) modeling system coupled with the Weather Research and Forecasting (WRF) model. Simulations with different biogenic isoprene emission scenarios show that the impact of biogenic isoprene emission on the daily maximum O-3 concentration is as high as 37 ppb in the Seoul region. The O-3 concentration in the Seoul region is significantly increased by the biogenic isoprene emission from the surrounding region compared to that from within the Seoul region. In addition, the gas-phase chemistry is found to be the most important process for O-3 concentration in the Seoul region in the presence of the biogenic isoprene emission from the surrounding region. While isoprene is not enough to influence O-3 concentration directly due to its short lifetime, the transport of isoprene oxidation products plays a crucial role in increasing O-3 concentration in the Seoul region. Through the process analysis, peroxy methacryloyl nitrate (MPAN) as well as formaldehyde (HCHO) and acetaldehyde (CCHO) is also identified as the important precursor that links biogenic isoprene emission from the surrounding region to O-3 concentration in the Seoul region. After transported by daytime local circulations, the chemistry of isoprene oxidation products contributes to O-3 formation in the Seoul region. (C) 2014 Elsevier Ltd. All rights reserved.11Nsciescopu