We systematically screened binary catalysts for synthesis of dimethyl carbonate (DMC) from CO(2), CH(3)OH and ethylene oxide (EO) in the presence of H(2)O by two-step transesterification process, and found the commercial quaternary ammonium salts/K(2)CO(3), pyridinium salts/K(2)CO(3) and KI/K(2)CO(3) were effective binary catalysts for two-step synthesis of DMC with no need for separation of ethylene carbonate (EC). Near 100% conversion of EO and 82% yield of DMC were obtained under mild reaction conditions. However, the imidazolium salts were not compatible with inorganic alkaline possibly because of the reactive C(2)-H in the imidazolium ring. Furthermore, the KI/K(2)CO(3) could be easily recovered and reused 12 times without obvious loss...
Several novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbon...
Dimethyl carbonate (DMC) has been used in synthetic organic chemistry as a low-toxicity and versatil...
The worldwide urge to embrace a sustainable and bio-compatible chemistry has led industry and academ...
We investigated the dependence of cations and anions of ionic liquids (ILs) on catalytic activity fo...
Continuous synthesis at ambient conditions: Dimethyl carbonate (DMC) is an important methylating and...
Herein, we report on the metal-free, one-pot synthesis of industrially important dimethyl carbonate ...
Dimethyl carbonate (DMC) is an established solvent and a green reagent which continues to attract at...
This review summarizes the performance of potential catalysts for the synthesis of dimethyl carbonat...
The direct synthesis of dimethyl carbonate (DMC) from carbon dioxide and methanol is an atom economi...
The reaction of carbon dioxide transformation is tremendously interesting in research societies from...
Dimethyl carbonate (DMC) and glycidol are considered industrially important chemical entities and th...
In this work, we have prepared two series of layered double hydroxides (LDHs) based on three differe...
At 90 °C, in the presence of CsF/alpha-Al2O3 or [P8,8,8,1][H3COCO2] as catalysts, a straightforward ...
Dimethyl carbonate is a generally used chemical substance which is environmentally sustainable in na...
Dialkyl carbonates are important industrial compounds that have a low toxicity and are readily biode...
Several novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbon...
Dimethyl carbonate (DMC) has been used in synthetic organic chemistry as a low-toxicity and versatil...
The worldwide urge to embrace a sustainable and bio-compatible chemistry has led industry and academ...
We investigated the dependence of cations and anions of ionic liquids (ILs) on catalytic activity fo...
Continuous synthesis at ambient conditions: Dimethyl carbonate (DMC) is an important methylating and...
Herein, we report on the metal-free, one-pot synthesis of industrially important dimethyl carbonate ...
Dimethyl carbonate (DMC) is an established solvent and a green reagent which continues to attract at...
This review summarizes the performance of potential catalysts for the synthesis of dimethyl carbonat...
The direct synthesis of dimethyl carbonate (DMC) from carbon dioxide and methanol is an atom economi...
The reaction of carbon dioxide transformation is tremendously interesting in research societies from...
Dimethyl carbonate (DMC) and glycidol are considered industrially important chemical entities and th...
In this work, we have prepared two series of layered double hydroxides (LDHs) based on three differe...
At 90 °C, in the presence of CsF/alpha-Al2O3 or [P8,8,8,1][H3COCO2] as catalysts, a straightforward ...
Dimethyl carbonate is a generally used chemical substance which is environmentally sustainable in na...
Dialkyl carbonates are important industrial compounds that have a low toxicity and are readily biode...
Several novel 2-hydroxymethyl-functionalized ILs act as the catalysts for synthesis of cyclic carbon...
Dimethyl carbonate (DMC) has been used in synthetic organic chemistry as a low-toxicity and versatil...
The worldwide urge to embrace a sustainable and bio-compatible chemistry has led industry and academ...